Author: Badral Gansukh

0000000000740617

AUTHOR

Badral Gansukh

The chloro‐substituent enhances performance of 2,4‐bis (imino)pyridylchromium catalysts yielding highly linear polyethylene

The five unsymmetrical 2‐[1‐(2,4‐dibenzhydryl‐6‐chlorophenylimino)ethyl]‐6‐[1‐(arylimino)ethyl]pyridine compounds (aryl: 2,6‐Me2Ph L1 , 2,6‐Et2Ph L2 , 2,6‐i Pr2Ph L3 , 2,4,6‐Me3Ph L4 and 2,6‐Et2–4‐MePh L5 ) were prepared and characterized with FT‐IR and 1H/13C NMR spectroscopy as well as elemental analysis. The treatment of L1 – L5 with CrCl3·3THF affords the corresponding chromium chloride complexes (Cr1 – Cr5 ) in excellent yields. The molecular structures of Cr2 and Cr3 characterized by X‐ray diffraction show a distorted octahedral geometry with three nitrogen atoms and three chlorine atoms around the metal center. On activation with either MAO or MMAO, Cr1 – Cr5 collectively display hig…

research product

CCDC 1951481: Experimental Crystal Structure Determination

Related Article: Badral Gansukh, Qiuyue Zhang, Zygmunt Flisak, Tongling Liang, Yanping Ma, Wen‐Hua Sun|2020|Appl.Organomet.Chem.|34|e5471|doi:10.1002/aoc.5471

research product

CCDC 1951482: Experimental Crystal Structure Determination

Related Article: Badral Gansukh, Qiuyue Zhang, Zygmunt Flisak, Tongling Liang, Yanping Ma, Wen‐Hua Sun|2020|Appl.Organomet.Chem.|34|e5471|doi:10.1002/aoc.5471

research product

PEPhysical Sciences and Engineering
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