Intra- and Interchain Correlations in Semidilute Polymer Solutions:  Monte Carlo Simulations and Renormalization Group Results

2000

We investigate the intra- and intermolecular correlations in semidilute polymer solutions by large-scale computer simulations and renormalization group calculations. In the framework of the bond fluctuation model we study polymers with chain lengths up to N = 2048 monomers and determine the intermolecular pair correlation function, the coherent scattering intensity, and its distinct part at all length scales. The simulations are compared quantitatively to renormalization group calculations of the universal crossover scaling function. Special attention is paid to length scales smaller than the density screening length ξ, where the distinct part of the scattering function in the simulations i…