0000000000746375

AUTHOR

Verónica Gironés-pérez

showing 6 related works from this author

Heteroleptic Iron(II) Spin-Crossover Complexes Based on a 2,6-Bis(pyrazol-1-yl)pyridine-type Ligand Functionalized with a Carboxylic Acid

2019

Two new heteroleptic complexes [Fe- (1bppCOOH)(3bpp-bph)](ClO4)2·solv (1·solv, solv = various solvents; 1bppCOOH = 2,6-bis(1H-pyrazol-1-yl)- isonicotinic acid; 3bpp-bph = 2,6-bis(5-([1,1′-biphenyl]-4- yl)-1H-pyrazol-3-yl)pyridine) and [Fe(1bppCOOH)- (1bppCOOEt)](ClO4)2 ·0.5Me2CO (2·0.5Me2CO, 1bppCOOEt = ethyl 2,6-bis(1H-pyrazol-1-yl)isonicotinate) were designed and prepared. The heteroleptic compound 1· solv was obtained by the combination of stoichiometric amounts of Fe(ClO4)2, 1bppCOOH, and 3bpp-bph, and it was designed to fine-tune the spin crossover (SCO) properties with respect to the previously reported homoleptic compound [Fe(1bppCOOH)2](ClO4)2. Indeed, the introduction of a new subs…

chemistry.chemical_classification010405 organic chemistryLigandCarboxylic acidEnllaços químicsQuímica organometàl·licaKetones010402 general chemistryIsonicotinic acidLigands01 natural sciencesMedicinal chemistry0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundLligandschemistrySpin crossoverCetonesPyridineCompostos de coordinacióPhysical and Theoretical ChemistryInorganic Chemistry
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CCDC 1917753: Experimental Crystal Structure Determination

2019

Related Article: Víctor García-López, Mario Palacios-Corella, Verónica Gironés-Pérez, Carlos Bartual-Murgui, José Antonio Real, Eric Pellegrin, Javier Herrero-Martín, Guillem Aromí, Miguel Clemente-León, Eugenio Coronado|2019|Inorg.Chem.|58|12199|doi:10.1021/acs.inorgchem.9b01526

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-[ethyl 26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylate]-iron(ii) bis(perchlorate) acetone solvateExperimental 3D Coordinates
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CCDC 1917752: Experimental Crystal Structure Determination

2019

Related Article: Víctor García-López, Mario Palacios-Corella, Verónica Gironés-Pérez, Carlos Bartual-Murgui, José Antonio Real, Eric Pellegrin, Javier Herrero-Martín, Guillem Aromí, Miguel Clemente-León, Eugenio Coronado|2019|Inorg.Chem.|58|12199|doi:10.1021/acs.inorgchem.9b01526

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters{26-bis[5-([11'-biphenyl]-4-yl)-1H-pyrazol-3-yl]pyridine}-[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(perchlorate) acetone solvateExperimental 3D Coordinates
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CCDC 1917754: Experimental Crystal Structure Determination

2019

Related Article: Víctor García-López, Mario Palacios-Corella, Verónica Gironés-Pérez, Carlos Bartual-Murgui, José Antonio Real, Eric Pellegrin, Javier Herrero-Martín, Guillem Aromí, Miguel Clemente-León, Eugenio Coronado|2019|Inorg.Chem.|58|12199|doi:10.1021/acs.inorgchem.9b01526

[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-[ethyl 26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylate]-iron bis(perchlorate) acetone solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1917750: Experimental Crystal Structure Determination

2019

Related Article: Víctor García-López, Mario Palacios-Corella, Verónica Gironés-Pérez, Carlos Bartual-Murgui, José Antonio Real, Eric Pellegrin, Javier Herrero-Martín, Guillem Aromí, Miguel Clemente-León, Eugenio Coronado|2019|Inorg.Chem.|58|12199|doi:10.1021/acs.inorgchem.9b01526

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters{26-bis[5-([11'-biphenyl]-4-yl)-1H-pyrazol-3-yl]pyridine}-[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(perchlorate) acetone diethyl ether solvateExperimental 3D Coordinates
researchProduct

CCDC 1917751: Experimental Crystal Structure Determination

2019

Related Article: Víctor García-López, Mario Palacios-Corella, Verónica Gironés-Pérez, Carlos Bartual-Murgui, José Antonio Real, Eric Pellegrin, Javier Herrero-Martín, Guillem Aromí, Miguel Clemente-León, Eugenio Coronado|2019|Inorg.Chem.|58|12199|doi:10.1021/acs.inorgchem.9b01526

{26-bis[5-([11'-biphenyl]-4-yl)-1H-pyrazol-3-yl]pyridine}-[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron bis(perchlorate) acetone solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct