Author: Jeffrey Ovens

0000000000747828

AUTHOR

Jeffrey Ovens

Asymmetric Ring Opening in Tetrazine‐based Ligand Affording a Tetranuclear Opto‐Magnetic Ytterbium Complex

We report the formation of a tetranuclear lanthanide cluster, [Yb 4 (bpzch) 2 (fod) 10 ] ( 1 ), which occurs from a serendipitous ring opening of the functionalized tetrazine bridging ligand, bpztz (3,6‐dipyrazin‐2‐yl‐1,2,4,5‐tetrazine) upon reacting with Yb(fod) 3 (fod ‐ = 6,6,7,7,8,8,8‐heptafluoro‐2,2‐dimethyl‐3,5‐octandionate). Compound 1 was structurally elucidated via single‐crystal X‐ray crystallography and subsequently magnetically and spectroscopically characterized to analyse its magnetisation dynamics and its luminescence behaviour. Computational studies validate the observed M J energy levels attained by spectroscopy and provides a clearer picture of the slow relaxation of the ma…

research product

CCDC 2026744: Experimental Crystal Structure Determination

Related Article: Paul Richardson, Riccardo Marin, Yixin Zhang, Bulat Gabidullin, Jeffrey Ovens, Jani O. Moilanen, Muralee Murugesu|2020|Chem.-Eur.J.|27|2361|doi:10.1002/chem.202003556

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PEPhysical Sciences and Engineering
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