0000000000754830

AUTHOR

Robert Mokrik

A δ18O isoscape for the shallow groundwater in the Baltic Artesian Basin

The study presents a shallow groundwater isoscape for the Baltic region, which covers the major part of the Baltic Artesian Basin (BAB). BAB is an important palaeogroundwater reservoir, but prior to this study, little has been known about the spatial variability of δD and δ18O values in modern precipitation input across the region. To overcome this limitation, we hypothesized that the isotopic composition of shallow groundwater in the BAB could be used as a proxy for the mean weighted annual isotopic composition of local precipitation. However, the results of the study reveal many clear discrepancies between the isotopic composition of precipitation and shallow groundwater in the area. The …

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Using 81Kr and Noble Gases to Characterize and Date Groundwater and Brines in the Baltic Artesian Basin on the One-Million-Year Timescale

Analyses for $^{81}$Kr and noble gases on groundwater from the deepest aquifer system of the Baltic Artesian Basin (BAB) were performed to determine groundwater ages and uncover the flow dynamics of the system on a timescale of several hundred thousand years. We find that the system is controlled by mixing of three distinct water masses: Interglacial or recent meteoric water $(\delta^{18}\text{O} \approx -10.4\unicode{x2030})$ with a poorly evolved chemical and noble gas signature, glacial meltwater $(\delta^{18}\text{O} \leq -18\unicode{x2030})$ with elevated noble gas concentrations, and an old, high-salinity brine component $(\delta^{18}\text{O} \geq -4.5\unicode{x2030}, \geq 90 \text{g …

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