Author: Takahiko Akiyama

0000000000756229

AUTHOR

Takahiko Akiyama

0000-0003-4709-4107

showing 2 related works from this author

γ-Silylboronates in the chiral Brønsted acid-catalysed allylboration of aldehydes.

2014

The use of functionalised allylboronic esters in the catalytic enantioselective allylboration of aldehydes is described for the first time. γ-Silylallyl pinacolate derivatives give rise to α-silyl homoallylic alcohols in high yields, with complete diastereoselectivities and high enantioselectivities, in most of the cases. The usefulness of such intermediates is showcased by their transformation into fluorinated allylic alcohols.

Allylic rearrangementStereochemistryChemistryMetals and AlloysEnantioselective synthesisGeneral ChemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCatalysisMaterials ChemistryCeramics and CompositesOrganic chemistryBrønsted–Lowry acid–base theoryChemical communications (Cambridge, England)

researchProduct

CCDC 1031785: Experimental Crystal Structure Determination

2014

Related Article: Pablo Barrio, Elsa Rodríguez, Kodai Saito, Santos Fustero, Takahiko Akiyama|2015|Chem.Commun.|51|5246|doi:10.1039/C4CC08598A

Space GroupCrystallography1-(4-nitrophenyl)-2-(trimethyl-lambda4-sulfanyl)but-3-en-1-olCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

researchProduct

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