0000000000759259

AUTHOR

James E. Anderson

showing 4 related works from this author

ChemInform Abstract: Synthesis and Electrode Reactions of Difluorogermanium(IV) Porphyrins. Molecular Stereochemistry and Crystal Structure of Difluo…

1988

The difluorogermanium(IV) porphyrins [GeF2(P)][P = 2,3,7,8,12,13,17,18-octaethylporphyrinate(2–)(oep), 5,10,15,20-tetraphenylporphyrinate(2–)(tpp), or 5,10,15,20-tetra-p-tolylporphyrinate(2–)(tptp)] have been prepared by reacting hydrogen fluoride with the appropriate dichloro derivative [GeCl2(P)]. The complexes were characterized by elemental analysis, 1H n.m.r., i.r., and u.v.–visible spectroscopy. The electrochemical behaviour was investigated in non-aqueous media while spectroelectrochemistry and e.s.r. were used to characterize the oxidized and reduced complexes. Each complex could be reversibly oxidized or reduced by one electron. In each case these electron additions or abstractions…

chemistry.chemical_compoundCrystallographychemistryFluorinechemistry.chemical_elementGermaniumGeneral MedicineCrystal structureHydrogen fluorideElectrochemistryRing (chemistry)PorphyrinDerivative (chemistry)ChemInform
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Electrochemistry and germanium porphyrins in nonaqueous media. Reactions of water and hydroxide ligands associated with (P)Ge(ClO4)2 and (P)Ge(OH)2, …

1988

Inorganic chemistrychemistry.chemical_elementGermaniumElectrochemistryMedicinal chemistryInorganic ChemistryBenzonitrilechemistry.chemical_compoundTransition metalchemistryTetraphenylporphyrinHydroxidePhysical and Theoretical ChemistryCyclic voltammetryPlatinumInorganic Chemistry
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Synthesis and electrode reactions of difluorogermanium(IV) porphyrins. Molecular stereochemistry and crystal structure of difluoro-(2,3,7,8,12,13,17,…

1988

The difluorogermanium(IV) porphyrins [GeF2(P)][P = 2,3,7,8,12,13,17,18-octaethylporphyrinate(2–)(oep), 5,10,15,20-tetraphenylporphyrinate(2–)(tpp), or 5,10,15,20-tetra-p-tolylporphyrinate(2–)(tptp)] have been prepared by reacting hydrogen fluoride with the appropriate dichloro derivative [GeCl2(P)]. The complexes were characterized by elemental analysis, 1H n.m.r., i.r., and u.v.–visible spectroscopy. The electrochemical behaviour was investigated in non-aqueous media while spectroelectrochemistry and e.s.r. were used to characterize the oxidized and reduced complexes. Each complex could be reversibly oxidized or reduced by one electron. In each case these electron additions or abstractions…

chemistry.chemical_classificationStereochemistryGeneral ChemistryCrystal structureRing (chemistry)Hydrogen fluoridePorphyrinchemistry.chemical_compoundCrystallographychemistryX-ray crystallographyMoleculeInorganic compoundDerivative (chemistry)Journal of the Chemical Society, Dalton Transactions
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Synthesis, photochemistry, and electrochemistry of (P)Ge(R)2 and (P)Ge(R)X (P = TPP or OEP, R = CH3, CH2C6H5, or C6H5, and X = Cl-, OH-, or ClO4-)

1987

Chaque complexe est caracterise par spectroscopie RMN de H1, UV-visible, IR et aussi par l'etude electrochimique

Colloid and Surface ChemistryChemistryStereochemistryGeneral ChemistryCyclic voltammetryElectrochemistryBiochemistryMedicinal chemistryCatalysisJournal of the American Chemical Society
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