ChemInform Abstract: Synthesis and Electrode Reactions of Difluorogermanium(IV) Porphyrins. Molecular Stereochemistry and Crystal Structure of Difluoro-(2,3,7,8,12,13,17,18-octaethylporphyrinato)germanium(IV).

The difluorogermanium(IV) porphyrins [GeF2(P)][P = 2,3,7,8,12,13,17,18-octaethylporphyrinate(2–)(oep), 5,10,15,20-tetraphenylporphyrinate(2–)(tpp), or 5,10,15,20-tetra-p-tolylporphyrinate(2–)(tptp)] have been prepared by reacting hydrogen fluoride with the appropriate dichloro derivative [GeCl2(P)]. The complexes were characterized by elemental analysis, 1H n.m.r., i.r., and u.v.–visible spectroscopy. The electrochemical behaviour was investigated in non-aqueous media while spectroelectrochemistry and e.s.r. were used to characterize the oxidized and reduced complexes. Each complex could be reversibly oxidized or reduced by one electron. In each case these electron additions or abstractions…

Electrochemistry and germanium porphyrins in nonaqueous media. Reactions of water and hydroxide ligands associated with (P)Ge(ClO4)2 and (P)Ge(OH)2, where P is the dianion of tetraphenylporphyrin (TPP) or octaethylporphyrin (OEP)

Synthesis and electrode reactions of difluorogermanium(IV) porphyrins. Molecular stereochemistry and crystal structure of difluoro-(2,3,7,8,12,13,17,18-octaethylporphyrinato)germanium(IV)

The difluorogermanium(IV) porphyrins [GeF2(P)][P = 2,3,7,8,12,13,17,18-octaethylporphyrinate(2–)(oep), 5,10,15,20-tetraphenylporphyrinate(2–)(tpp), or 5,10,15,20-tetra-p-tolylporphyrinate(2–)(tptp)] have been prepared by reacting hydrogen fluoride with the appropriate dichloro derivative [GeCl2(P)]. The complexes were characterized by elemental analysis, 1H n.m.r., i.r., and u.v.–visible spectroscopy. The electrochemical behaviour was investigated in non-aqueous media while spectroelectrochemistry and e.s.r. were used to characterize the oxidized and reduced complexes. Each complex could be reversibly oxidized or reduced by one electron. In each case these electron additions or abstractions…

Synthesis, photochemistry, and electrochemistry of (P)Ge(R)2 and (P)Ge(R)X (P = TPP or OEP, R = CH3, CH2C6H5, or C6H5, and X = Cl-, OH-, or ClO4-)

Chaque complexe est caracterise par spectroscopie RMN de H1, UV-visible, IR et aussi par l'etude electrochimique