0000000000760447
AUTHOR
M.d. Soriano
Selective oxidation of propane over alkali-doped Mo-V-Sb-O catalysts
[EN] Alkali metal-doped MoVSbO catalysts have been prepared by impregnation of a MoVSbO-mixed oxide (prepared previously by a hydrothermal synthesis) and finally activated at 500 or 600 degrees C in N-2. The catalysts have been characterized and tested for the selective oxidation of propane and propylene. Alkali-doped catalysts improved in general the catalytic performance of MoVSbO, resulting more selective to acrylic acid and less selective to acetic acid than the corresponding alkali-free MoVSbO catalysts. However, the specific behaviour strongly depends on both the alkali metal added and/or the final activation temperature. At isoconversion conditions, catalysts activated at 600 degrees…
The Impact of Climatic Change and Land Use on the Hydrological Response of Mediterranean Soils; a Study along a Climatological Gradient in Crete (Greece)
Abstract To help understand the impact of Climatic Change on the soils of the Mediterranean area, measurements of physical soil properties were carried out in a mountain zone in Crete (Greece), following a climatological gradient. Four experimental slopes were chosen, south facing and situated on limestone lithology. Soil hydrological properties including infiltration, runoff and sediment concentration, were measured and the percentage of waterstable microaggregation in the soil was calculated and used as an indicator of soil degradation. It was found that as well as climate, soil properties were highly affected by the extensive land use of the area, intensive grazing by goats and small sca…