0000000000770679
AUTHOR
Catherine Boussard-plédel
Positron annihilation probing of crystallization effects in TAS-235 glass affected by Ga additions
Abstract Crystallization effects in Te20As30Se50 glass known also as TAS-235 affected by Ga additions to Ga2Te20As28Se50 and Ga5Te20As25Se50 compositions are probed with positron annihilation spectroscopy in the measuring modes exploring positron lifetimes and Doppler broadening of annihilation line. Occurring of cubic-phase Ga2Se3 droplets with character nanoscale sizes in partially-crystallized Ga2Te20As28Se50 alloy is shown to be associated with agglomeration of intrinsic free-volume voids, this process being enhanced over microcrystalline scale in Ga5Te20As25Se50 alloy. Crystallization changes in the void structure of TAS-235 glass are considered in terms of free-volume evolution under …
Infrared monitoring of underground CO2 storage using chalcogenide glass fibers
International audience; An optical-fiber-based system suitable for monitoring the presence of carbon dioxide, so-called "greenhouse gas", is investigated. Since each pollutant gas shows a characteristic optical absorption spectrum in the mid-infrared (mid-IR), it is possible to detect selectively and quantitatively the presence of gases in a given environment by analysing mid-IR spectra. The main infrared signature of carbon dioxide gas is a double absorption peak located at 4.2 μm. Chalcogenide optical fibers, which can transmit light in the 1-6 μm range, are well-adapted for CO2 analysis. In this wavelength range, they show attenuation losses that compare favourably with other types of fi…