0000000000772091

AUTHOR

Zsolt Kelemen

showing 7 related works from this author

Icosahedral carboranes as scaffolds for congested regioselective polyaryl compounds : the distinct distance tuning of C-C and its antipodal B-B

2019

Four-fold aryl substituted o-carborane derivatives with defined patterns of substitution at the antipodal region of the cluster carbon atoms have been achieved. It is proven that this region is congested but lacks steric hindrance. Also, the two antipodal sites Cc-Cc and B9-B12 are affected very distinctly by electron donor substituents. peerReviewed

klusteritcarboraneskemialliset yhdisteetbooricluster compounds
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Icosahedral carboranes as scaffolds for congested regioselective polyaryl compounds: the distinct distance tuning of C–C and its antipodal B–B

2019

Four-fold aryl substituted o-carborane derivatives with defined patterns of substitution at the antipodal region of the cluster carbon atoms have been achieved. It is proven that this region is congested but lacks steric hindrance. Also, the two antipodal sites Cc–Cc and B9–B12 are affected very distinctly by electron donor substituents.

Steric effectsIcosahedral symmetryAntipodal pointElectron donorCrystal structure010402 general chemistry01 natural sciencesCatalysischemistry.chemical_compoundMaterials ChemistryCluster (physics)BoronO-carboranes010405 organic chemistryChemistryArylMetals and AlloysRegioselectivityGeneral Chemistry3. Good health0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsPharmacophoresCrystallographyCrystal-structureCeramics and CompositesChemical Communications
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CCDC 1913783: Experimental Crystal Structure Determination

2019

Related Article: Zsolt Kelemen, Ariadna Pepiol, Marius Lupu, Reijo Sillanpää, Mikko M. Hänninen, Francesc Teixidor, Clara Viñas|2019|Chem.Commun.|55|8927|doi:10.1039/C9CC04526K

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters912-bis(4-formylphenyl)-12-dicarba-closo-dodecaborane(10)Experimental 3D Coordinates
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CCDC 1913782: Experimental Crystal Structure Determination

2019

Related Article: Zsolt Kelemen, Ariadna Pepiol, Marius Lupu, Reijo Sillanpää, Mikko M. Hänninen, Francesc Teixidor, Clara Viñas|2019|Chem.Commun.|55|8927|doi:10.1039/C9CC04526K

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters912-bis(4-(dimethoxymethyl)phenyl)-12-dicarba-closo-dodecaborane(10)Experimental 3D Coordinates
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CCDC 1562911: Experimental Crystal Structure Determination

2019

Related Article: Zsolt Kelemen, Ariadna Pepiol, Marius Lupu, Reijo Sillanpää, Mikko M. Hänninen, Francesc Teixidor, Clara Viñas|2019|Chem.Commun.|55|8927|doi:10.1039/C9CC04526K

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters912-diallyl-810-diphenyl-12-dicarba-closo-dodecaborane(8) chloroform solvateExperimental 3D Coordinates
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CCDC 1871938: Experimental Crystal Structure Determination

2019

Related Article: Zsolt Kelemen, Ariadna Pepiol, Marius Lupu, Reijo Sillanpää, Mikko M. Hänninen, Francesc Teixidor, Clara Viñas|2019|Chem.Commun.|55|8927|doi:10.1039/C9CC04526K

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters81012-triphenyl-9-iodo-12-dicarba-closo-dodecaborane(8)Experimental 3D Coordinates
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CCDC 1871937: Experimental Crystal Structure Determination

2019

Related Article: Zsolt Kelemen, Ariadna Pepiol, Marius Lupu, Reijo Sillanpää, Mikko M. Hänninen, Francesc Teixidor, Clara Viñas|2019|Chem.Commun.|55|8927|doi:10.1039/C9CC04526K

Space GroupCrystallography891012-tetraphenyl-12-dicarba-closo-dodecaborane(8)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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