0000000000787663

AUTHOR

V. Parra

showing 2 related works from this author

Molecular semiconductor-doped insulator (MSDI) heterojunctions as new transducers for chemical sensors

2011

International audience; This article describes a new principle of transduction involving an heterojunction between a Molecular Semiconductor and a Doped Insulator (MSDI). Herein, we report on an MSDI-based sensor featuring an heterojunction between a lutetium bisphthalocyanine (LuPc), which acts as Molecular Semiconductor (MS) and a thin film of Doped Insulator (DI) made of substituted or fluorinated copper phthalocyanine (CuFPc, where = 0, 8, 16). Previously, we reported the peculiar effect of the heterojunction on the MSDI's electronic behavior, suggesting this device as a new kind of transducer for gas chemosensing. Indeed, of particular significance was the key role of modulator played …

[PHYS]Physics [physics]Materials sciencebusiness.industryAmbipolar diffusionDopingNanotechnologyInsulator (electricity)Heterojunction02 engineering and technologyElectron010402 general chemistry021001 nanoscience & nanotechnologyCondensed Matter Physics01 natural sciencesEffective nuclear charge0104 chemical sciencesElectronic Optical and Magnetic MaterialsPhysical SciencesOptoelectronicsThin film0210 nano-technologySpectroscopybusinessInstrumentation
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PV effect of fullerene/poly(3-hexylthiophene) blend sensitized by phthalocyanine having infrared absorption CT band

2008

An attempt was made to extend the photosensitivity spectral range of fullerene/poly(3-hexylthiophene) blend to NIR region by adding extra electron donor — hydroxygallium phthalocyanine (GaOHPc) with a strong and wide intermolecular charge transfer (CT) band around 830 nm. Multilayer cells of ITO/PEDOT: PSS/6 GaOHPc/P3HT: C61(CO2Et)2 have been prepared by spin coating with vacuum evaporated Al or In top electrodes. Significant photosensitivity of the cells was in 370–900 nm spectral range. However charge carrier photogeneration efficiency was 3 times higher for illumination in P3HT absorption band as compared with the GaOHPc CT band at 830 nm. But when GaOHPc was mixed in the blend forming P…

Spin coatingMaterials sciencebusiness.industryPhotochemistryPolymer solar cellchemistry.chemical_compoundPhotosensitivityPEDOT:PSSchemistryAbsorption bandPhthalocyanineOptoelectronicsQuantum efficiencyCharge carrierbusiness
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