0000000000793639
AUTHOR
M Jansons
Quasi-resonant energy transfer in collisions: Na2(A1? u + )+K(4S)
Cross sections for electron energy transfer from the initial rotational stateJ′of the two lowest vibrational levelsv′=0 andv′=1 of excited dimers Na2(A) to potassium atoms as described by Na2(A1Σu+,v′J′)+K(4S)→Na2 (X1Σg+,v″J″)+K(4P)+ΔE have been examined by laser-induced fluorescence. A strong increase of the cross section by as much as an order of magnitude has been observed for those dimerv′J′-levels for which the dipole transitions are close to resonance of the 4S-4P transitions in the atom (ΔE<4 cm−1). The absolute cross sections for energy transfer have been calculated by the Rabitz approximation of first-order perturbation theory. In the case of closest energy resonance (ΔE=0.9 cm−1) …
Studies of inelastic cross-section in Rb(7S) + Rb(5S) collisions
The cross section σ = (8 ± 4) × 10−15 cm2 was determined for the Rb(7S) + Rb(5S) → Rb(5D) + Rb(5S) excitation energy transfer process, and the quenching cross section σq = (2 ± 1) × 10−14 cm2 for the Rb(5D) state in collisions with ground state Rb atoms. Applying rubidium quasimolecular asymptotic potential curves at relatively large internuclear distances, a qualitative interpretation of the experimental results is presented. It is shown that the quenching of the Rb(5D) atoms in collisions may be explained by a reversed energy pooling process Rb(5D) + Rb(5S) → Rb(5P) + Rb(5P).