0000000000798735
AUTHOR
K. Rissanen
Extended dipyrrin ligands : candidates for optical metal ion detection under competitive conditions
Acylhydrazone based extended dipyrrins L1-H and L2-H are introduced as complexometric ppb sensitive metal ion detectors. The binding of lanthanide, transition as well as post-transition metal ions is followed by UV-Vis measurements. The carbohydrate based ligand L2 is water soluble and thus can act as a metal ion sensor in this medium.
One‐pot synthesis of [2+2]‐helicate‐like macrocycle and 2+4‐μ4‐oxo tetranuclear open frame complexes : Chiroptical properties and asymmetric oxidative coupling of 2‐naphthols
Synthesis of binuclear Cu(II) terminally closed [2+2]‐ double‐stranded helicate‐like macrocycles 1, 1′,1″, 2, 2′, 2″ and 2+4‐μ4‐oxo tetranuclear open frame complexes 3, 3′, 3″, 4, 4′, 4″ are established. Adapting one‐pot self‐assembly technique from simple three components systems: 1,1′‐binaphthyl‐2,2′‐diamine, 4‐methyl‐2,6‐diformyl phenol and cupric salts, the helicate‐like [2+2]‐ macrocyclic complexes 1–1″, 2–2″ and 2+4‐μ4‐oxo tetranuclear complexes 3–3″, 4–4″ were obtained by appropriately altering the reaction condition such as temperature and subcomponent ratio. Density Functional Theory (DFT) calculations were carried out for understanding the structural geometries, intermediates invo…
CCDC 619713: Experimental Crystal Structure Determination
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CCDC 261836: Experimental Crystal Structure Determination
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CCDC 227628: Experimental Crystal Structure Determination
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CCDC 1425265: Experimental Crystal Structure Determination
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CCDC 249810: Experimental Crystal Structure Determination
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CCDC 205509: Experimental Crystal Structure Determination
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CCDC 249811: Experimental Crystal Structure Determination
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CCDC 934805: Experimental Crystal Structure Determination
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CCDC 245913: Experimental Crystal Structure Determination
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CCDC 104280: Experimental Crystal Structure Determination
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CCDC 903565: Experimental Crystal Structure Determination
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CCDC 611014: Experimental Crystal Structure Determination
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CCDC 645086: Experimental Crystal Structure Determination
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CCDC 103319: Experimental Crystal Structure Determination
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CCDC 1520476: Experimental Crystal Structure Determination
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CCDC 245909: Experimental Crystal Structure Determination
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CCDC 880529: Experimental Crystal Structure Determination
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CCDC 200083: Experimental Crystal Structure Determination
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CCDC 275031: Experimental Crystal Structure Determination
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CCDC 245918: Experimental Crystal Structure Determination
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CCDC 200081: Experimental Crystal Structure Determination
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CCDC 791508: Experimental Crystal Structure Determination
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CCDC 104621: Experimental Crystal Structure Determination
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CCDC 282422: Experimental Crystal Structure Determination
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CCDC 258947: Experimental Crystal Structure Determination
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CCDC 200075: Experimental Crystal Structure Determination
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CCDC 779161: Experimental Crystal Structure Determination
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CCDC 152579: Experimental Crystal Structure Determination
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CCDC 229367: Experimental Crystal Structure Determination
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CCDC 153053: Experimental Crystal Structure Determination
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CCDC 212549: Experimental Crystal Structure Determination
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CCDC 272717: Experimental Crystal Structure Determination
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CCDC 244861: Experimental Crystal Structure Determination
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CCDC 608116: Experimental Crystal Structure Determination
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CCDC 245912: Experimental Crystal Structure Determination
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CCDC 742171: Experimental Crystal Structure Determination
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CCDC 857694: Experimental Crystal Structure Determination
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CCDC 200077: Experimental Crystal Structure Determination
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CCDC 620721: Experimental Crystal Structure Determination
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CCDC 717658: Experimental Crystal Structure Determination
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CCDC 637679: Experimental Crystal Structure Determination
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CCDC 855775: Experimental Crystal Structure Determination
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CCDC 1409610: Experimental Crystal Structure Determination
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CCDC 903563: Experimental Crystal Structure Determination
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CCDC 752835: Experimental Crystal Structure Determination
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CCDC 1425257: Experimental Crystal Structure Determination
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CCDC 709470: Experimental Crystal Structure Determination
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CCDC 149026: Experimental Crystal Structure Determination
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CCDC 879940: Experimental Crystal Structure Determination
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CCDC 666839: Experimental Crystal Structure Determination
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CCDC 880530: Experimental Crystal Structure Determination
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CCDC 250578: Experimental Crystal Structure Determination
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CCDC 194904: Experimental Crystal Structure Determination
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CCDC 799323: Experimental Crystal Structure Determination
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CCDC 907249: Experimental Crystal Structure Determination
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CCDC 830168: Experimental Crystal Structure Determination
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CCDC 1053111: Experimental Crystal Structure Determination
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CCDC 210592: Experimental Crystal Structure Determination
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CCDC 208696: Experimental Crystal Structure Determination
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CCDC 220737: Experimental Crystal Structure Determination
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CCDC 855773: Experimental Crystal Structure Determination
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CCDC 690123: Experimental Crystal Structure Determination
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CCDC 258946: Experimental Crystal Structure Determination
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CCDC 1540569: Experimental Crystal Structure Determination
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CCDC 209379: Experimental Crystal Structure Determination
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CCDC 907250: Experimental Crystal Structure Determination
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CCDC 879939: Experimental Crystal Structure Determination
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CCDC 880526: Experimental Crystal Structure Determination
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CCDC 855069: Experimental Crystal Structure Determination
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CCDC 203385: Experimental Crystal Structure Determination
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CCDC 826148: Experimental Crystal Structure Determination
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CCDC 127935: Experimental Crystal Structure Determination
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CCDC 742169: Experimental Crystal Structure Determination
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CCDC 817434: Experimental Crystal Structure Determination
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CCDC 778508: Experimental Crystal Structure Determination
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CCDC 1021703: Experimental Crystal Structure Determination
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CCDC 776223: Experimental Crystal Structure Determination
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CCDC 868496: Experimental Crystal Structure Determination
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CCDC 127936: Experimental Crystal Structure Determination
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CCDC 637559: Experimental Crystal Structure Determination
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CCDC 275032: Experimental Crystal Structure Determination
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CCDC 149023: Experimental Crystal Structure Determination
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CCDC 743342: Experimental Crystal Structure Determination
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CCDC 196764: Experimental Crystal Structure Determination
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CCDC 200660: Experimental Crystal Structure Determination
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CCDC 244863: Experimental Crystal Structure Determination
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CCDC 181699: Experimental Crystal Structure Determination
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CCDC 690125: Experimental Crystal Structure Determination
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CCDC 210523: Experimental Crystal Structure Determination
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CCDC 1425262: Experimental Crystal Structure Determination
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CCDC 144907: Experimental Crystal Structure Determination
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CCDC 138601: Experimental Crystal Structure Determination
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CCDC 791507: Experimental Crystal Structure Determination
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CCDC 879937: Experimental Crystal Structure Determination
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CCDC 144909: Experimental Crystal Structure Determination
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CCDC 910388: Experimental Crystal Structure Determination
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CCDC 876910: Experimental Crystal Structure Determination
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CCDC 239890: Experimental Crystal Structure Determination
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CCDC 854385: Experimental Crystal Structure Determination
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CCDC 188429: Experimental Crystal Structure Determination
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CCDC 817435: Experimental Crystal Structure Determination
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CCDC 899063: Experimental Crystal Structure Determination
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CCDC 854384: Experimental Crystal Structure Determination
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CCDC 685194: Experimental Crystal Structure Determination
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CCDC 144908: Experimental Crystal Structure Determination
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CCDC 780776: Experimental Crystal Structure Determination
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CCDC 205462: Experimental Crystal Structure Determination
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CCDC 633847: Experimental Crystal Structure Determination
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CCDC 161426: Experimental Crystal Structure Determination
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CCDC 799324: Experimental Crystal Structure Determination
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CCDC 140070: Experimental Crystal Structure Determination
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CCDC 831305: Experimental Crystal Structure Determination
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CCDC 752838: Experimental Crystal Structure Determination
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CCDC 831302: Experimental Crystal Structure Determination
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CCDC 227629: Experimental Crystal Structure Determination
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CCDC 637565: Experimental Crystal Structure Determination
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CCDC 673203: Experimental Crystal Structure Determination
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CCDC 143449: Experimental Crystal Structure Determination
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CCDC 910391: Experimental Crystal Structure Determination
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CCDC 245910: Experimental Crystal Structure Determination
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CCDC 250235: Experimental Crystal Structure Determination
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CCDC 860617: Experimental Crystal Structure Determination
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CCDC 245914: Experimental Crystal Structure Determination
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CCDC 637678: Experimental Crystal Structure Determination
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CCDC 149024: Experimental Crystal Structure Determination
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CCDC 104619: Experimental Crystal Structure Determination
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CCDC 826152: Experimental Crystal Structure Determination
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CCDC 1027141: Experimental Crystal Structure Determination
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CCDC 755087: Experimental Crystal Structure Determination
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CCDC 186370: Experimental Crystal Structure Determination
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CCDC 611016: Experimental Crystal Structure Determination
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CCDC 229366: Experimental Crystal Structure Determination
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CCDC 205507: Experimental Crystal Structure Determination
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CCDC 780772: Experimental Crystal Structure Determination
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CCDC 706838: Experimental Crystal Structure Determination
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CCDC 156977: Experimental Crystal Structure Determination
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CCDC 745349: Experimental Crystal Structure Determination
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CCDC 254962: Experimental Crystal Structure Determination
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CCDC 910392: Experimental Crystal Structure Determination
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CCDC 644918: Experimental Crystal Structure Determination
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CCDC 903572: Experimental Crystal Structure Determination
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CCDC 250233: Experimental Crystal Structure Determination
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CCDC 826154: Experimental Crystal Structure Determination
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CCDC 209377: Experimental Crystal Structure Determination
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CCDC 876912: Experimental Crystal Structure Determination
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CCDC 705882: Experimental Crystal Structure Determination
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CCDC 149022: Experimental Crystal Structure Determination
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CCDC 127934: Experimental Crystal Structure Determination
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CCDC 208697: Experimental Crystal Structure Determination
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CCDC 208912: Experimental Crystal Structure Determination
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CCDC 254961: Experimental Crystal Structure Determination
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CCDC 186369: Experimental Crystal Structure Determination
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CCDC 757069: Experimental Crystal Structure Determination
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CCDC 620597: Experimental Crystal Structure Determination
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CCDC 1425260: Experimental Crystal Structure Determination
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CCDC 210590: Experimental Crystal Structure Determination
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CCDC 864207: Experimental Crystal Structure Determination
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CCDC 140069: Experimental Crystal Structure Determination
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CCDC 156976: Experimental Crystal Structure Determination
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CCDC 840207: Experimental Crystal Structure Determination
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CCDC 637562: Experimental Crystal Structure Determination
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CCDC 280353: Experimental Crystal Structure Determination
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CCDC 194240: Experimental Crystal Structure Determination
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CCDC 692125: Experimental Crystal Structure Determination
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CCDC 826150: Experimental Crystal Structure Determination
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CCDC 705884: Experimental Crystal Structure Determination
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CCDC 821711: Experimental Crystal Structure Determination
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CCDC 855774: Experimental Crystal Structure Determination
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CCDC 906911: Experimental Crystal Structure Determination
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CCDC 144906: Experimental Crystal Structure Determination
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CCDC 817433: Experimental Crystal Structure Determination
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CCDC 245916: Experimental Crystal Structure Determination
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CCDC 822002: Experimental Crystal Structure Determination
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CCDC 645088: Experimental Crystal Structure Determination
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CCDC 181702: Experimental Crystal Structure Determination
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CCDC 797132: Experimental Crystal Structure Determination
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CCDC 781080: Experimental Crystal Structure Determination
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CCDC 275026: Experimental Crystal Structure Determination
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CCDC 687761: Experimental Crystal Structure Determination
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CCDC 637561: Experimental Crystal Structure Determination
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CCDC 633849: Experimental Crystal Structure Determination
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CCDC 872224: Experimental Crystal Structure Determination
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CCDC 752831: Experimental Crystal Structure Determination
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CCDC 868497: Experimental Crystal Structure Determination
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CCDC 729713: Experimental Crystal Structure Determination
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CCDC 152523: Experimental Crystal Structure Determination
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CCDC 725579: Experimental Crystal Structure Determination
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CCDC 791511: Experimental Crystal Structure Determination
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CCDC 275027: Experimental Crystal Structure Determination
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CCDC 1409611: Experimental Crystal Structure Determination
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CCDC 831306: Experimental Crystal Structure Determination
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CCDC 215705: Experimental Crystal Structure Determination
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CCDC 779160: Experimental Crystal Structure Determination
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CCDC 150121: Experimental Crystal Structure Determination
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CCDC 866137: Experimental Crystal Structure Determination
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CCDC 103376: Experimental Crystal Structure Determination
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CCDC 250237: Experimental Crystal Structure Determination
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CCDC 200082: Experimental Crystal Structure Determination
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CCDC 245908: Experimental Crystal Structure Determination
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CCDC 630672: Experimental Crystal Structure Determination
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CCDC 879938: Experimental Crystal Structure Determination
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CCDC 196107: Experimental Crystal Structure Determination
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CCDC 907244: Experimental Crystal Structure Determination
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CCDC 143451: Experimental Crystal Structure Determination
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CCDC 903567: Experimental Crystal Structure Determination
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CCDC 233978: Experimental Crystal Structure Determination
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CCDC 154791: Experimental Crystal Structure Determination
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CCDC 774614: Experimental Crystal Structure Determination
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CCDC 127933: Experimental Crystal Structure Determination
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CCDC 200661: Experimental Crystal Structure Determination
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CCDC 272716: Experimental Crystal Structure Determination
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CCDC 244862: Experimental Crystal Structure Determination
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CCDC 258945: Experimental Crystal Structure Determination
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CCDC 172703: Experimental Crystal Structure Determination
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CCDC 826153: Experimental Crystal Structure Determination
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CCDC 786735: Experimental Crystal Structure Determination
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CCDC 853880: Experimental Crystal Structure Determination
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CCDC 821712: Experimental Crystal Structure Determination
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CCDC 210593: Experimental Crystal Structure Determination
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CCDC 864202: Experimental Crystal Structure Determination
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CCDC 879934: Experimental Crystal Structure Determination
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CCDC 1425268: Experimental Crystal Structure Determination
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CCDC 611015: Experimental Crystal Structure Determination
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CCDC 822459: Experimental Crystal Structure Determination
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CCDC 280352: Experimental Crystal Structure Determination
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