Synthesis and Holographic Properties of Alkyl 2-Cyanoacetate Acceptor Fragment Containing Push – Pull Type Organic Glasses

2015

We present synthesis, optical and holographic properties of original structure organic glasses based on compounds consisting of three fragments: of N,N-bis(2-(trityloxy)ethyl)-4-vinylaniline or N,N-bis(5,5,5-triphenylpentyl)-4-vinylaniline fragments as electron donating fragment (D), 4H-pyran-4-ylidene fragment as linker(π) and of 2-(trityloxy)ethyl 2-cyanoacetate or 5,5,5-triphenylpentyl 2-cyanoacetate as acceptor (A) fragment. These push-pull (D- π-A) type molecular compounds show good solubility in non-polar solvents (CHCl3 or CH2Cl2) and neat thin films with sufficient optical qualities have been obtained by spin-coating technique. Maxima of UV–VIS absorption in dichloromethane solution…