0000000000803198
AUTHOR
Natasha F. Sciortino
showing 9 related works from this author
An investigation of photo- and pressure-induced effects in a pair of isostructural two-dimensional spin-crossover framework materials
2014
International audience; Two new isostructural iron(II) spin-crossover (SCO) framework (SCOF) materials of the type [Fe(dpms)2 (NCX)2 ] (dpms=4,4'-dipyridylmethyl sulfide; X=S (SCOF-6(S)), X=Se (SCOF-6(Se))) have been synthesized. The 2D framework materials consist of undulating and interpenetrated rhomboid (4,4) nets. SCOF-6(S) displays an incomplete SCO transition with only approximately 30 % conversion of high-spin (HS) to low-spin iron(II) sites over the temperature range 300-4 K (T1/2 =75 K). In contrast, the NCSe(-) analogue, SCOF-6(Se), displays a complete SCO transition (T1/2 =135 K). Photomagnetic characterizations reveal quantitative light- induced excited spin-state trapping (LIES…
Exploiting Pressure To Induce a "Guest-Blocked" Spin Transition in a Framework Material.
2016
A new functionalized 1,2,4-triazole ligand, 4-[(E)-2-(5-methyl-2-thienyl)vinyl]-1,2,4-triazole (thiome), was prepared to assess the broad applicability of strategically producing multistep spin transitions in two-dimensional Hofmann-type materials of the type [FeIIPd(CN)4(R-1,2,4-trz)2]·nH2O (R-1,2,4-trz = a 4-functionalized 1,2,4-triazole ligand). A variety of structural and magnetic investigations on the resultant framework material [FeIIPd(CN)4(thiome)2]·2H2O (A·2H2O) reveal that a high-spin (HS) to low-spin (LS) transition is inhibited in A·2H2O due to a combination of guest and ligand steric bulk effects. The water molecules can be reversibly removed with retention of the porous host f…
CCDC 1480120: Experimental Crystal Structure Determination
2016
Related Article: Natasha F. Sciortino, Florence Ragon, Katrina A. Zenere, Peter D. Southon, Gregory J. Halder, Karena W. Chapman, Lucía Piñeiro-López, José A. Real, Cameron J. Kepert, and Suzanne M. Neville|2016|Inorg.Chem.|55|10490|doi:10.1021/acs.inorgchem.6b01686
CCDC 1480121: Experimental Crystal Structure Determination
2016
Related Article: Natasha F. Sciortino, Florence Ragon, Katrina A. Zenere, Peter D. Southon, Gregory J. Halder, Karena W. Chapman, Lucía Piñeiro-López, José A. Real, Cameron J. Kepert, and Suzanne M. Neville|2016|Inorg.Chem.|55|10490|doi:10.1021/acs.inorgchem.6b01686
CCDC 1480123: Experimental Crystal Structure Determination
2016
Related Article: Natasha F. Sciortino, Florence Ragon, Katrina A. Zenere, Peter D. Southon, Gregory J. Halder, Karena W. Chapman, Lucía Piñeiro-López, José A. Real, Cameron J. Kepert, and Suzanne M. Neville|2016|Inorg.Chem.|55|10490|doi:10.1021/acs.inorgchem.6b01686
CCDC 955785: Experimental Crystal Structure Determination
2014
Related Article: Natasha F. Sciortino, Suzanne M. Neville, Cedric Desplanches, Jean Francois Letard, Victor Martinez, Jose Antonio Real, Boujemaa Moubaraki, Keith Murray, Cameron J. Kepert|2014|Chem.-Eur.J.|20|7448|doi:10.1002/chem.201400367
CCDC 955786: Experimental Crystal Structure Determination
2014
Related Article: Natasha F. Sciortino, Suzanne M. Neville, Cedric Desplanches, Jean Francois Letard, Victor Martinez, Jose Antonio Real, Boujemaa Moubaraki, Keith Murray, Cameron J. Kepert|2014|Chem.-Eur.J.|20|7448|doi:10.1002/chem.201400367
CCDC 1480122: Experimental Crystal Structure Determination
2016
Related Article: Natasha F. Sciortino, Florence Ragon, Katrina A. Zenere, Peter D. Southon, Gregory J. Halder, Karena W. Chapman, Lucía Piñeiro-López, José A. Real, Cameron J. Kepert, and Suzanne M. Neville|2016|Inorg.Chem.|55|10490|doi:10.1021/acs.inorgchem.6b01686
CCDC 955784: Experimental Crystal Structure Determination
2014
Related Article: Natasha F. Sciortino, Suzanne M. Neville, Cedric Desplanches, Jean Francois Letard, Victor Martinez, Jose Antonio Real, Boujemaa Moubaraki, Keith Murray, Cameron J. Kepert|2014|Chem.-Eur.J.|20|7448|doi:10.1002/chem.201400367