0000000000803209
AUTHOR
Leonid Dubrovinsky
Synthesis and High-Pressure Study of Corundum-Type In2O3
This work reports the high-pressure and high-temperature (HP-HT) synthesis of pure rhombohedral (corundum-type) phase of indium oxide (In2O3) from its most stable polymorph, cubic bixbyite-type In2O3, using a multianvil press. Structural and vibrational properties of corundum-type In2O3 (rh-In2O3) have been characterized by means of angle-dispersive powder X-ray diffraction and Raman scattering measurements at high pressures which have been compared to structural and lattice dynamics ab initio calculations. The equation of state and the pressure dependence of the Raman-active modes of the corundum-type phase are reported and compared to those of corundum (α-Al2O3). It can be concluded that …
In situ micro-Raman and X-ray diffraction study of diamonds and petrology of the new ureilite UAE 001 from the United Arab Emirates
International audience; A new olivine-pigeonite ureilite containing abundant diamonds and graphite was found in the United Arab Emirates. This is the first report of a meteorite in this country. The sample is heavily altered, of medium shock level, and has a total weight of 155 g. Bulk rock, olivine (Fo79.8-81.8) and pyroxene (En73.9-75.2, Fs15.5-16.9, Wo8.8-9.5) compositions are typical of ureilites. Olivine rims are reduced with Fo increasing up to Fo96.1-96.8. Metal in these rims is completely altered to Fehydroxide during terrestrial weathering. We studied diamond and graphite using micro-Raman and in situ synchrotron X-ray diffraction. The main diamond Raman band (LO=TO mode at ~1332 c…