0000000000809733

AUTHOR

Daoud Naoufal

showing 27 related works from this author

Aminomethyl-Substituted Ferrocenes and Derivatives: Straightforward Synthetic Routes, Structural Characterization, and Electrochemical Analysis

2013

A variety of aminomethyl-substituted ferrocenes and the parent compounds (iminomethyl)ferrocenes, azaferrocenophanes, and diferrocenylamines can be selectively synthesized from reductive amination of 1,1′-diformylferrocene or formylferrocene. The optimized one- or two-step reactions have delivered 13 new compounds, isolated in 65–97% yields, which include tertiary (ferrocenylmethyl)amines and azaferrocenophanes by using NaBH(OAc)3 as a mild reducing agent and (iminomethyl)ferrocenes and secondary (ferrocenylmethyl)amines by using LiAlH4. X-ray structures of representative members of these ferrocene derivative families have evidenced the preferred conformation adopted by ferrocene backbones,…

Steric effectsNitromethaneReducing agentChemistryOrganic ChemistryElectrochemistryReductive aminationCombinatorial chemistryInorganic Chemistrychemistry.chemical_compoundFerroceneOrganic chemistryFerrocene derivativesPhysical and Theoretical ChemistryCyclic voltammetryOrganometallics
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Ferrocenyl (P,N)-diphosphines incorporating pyrrolyl, imidazolyl or benzazaphospholyl moieties: Synthesis, coordination to group 10 metals and perfor…

2013

Abstract Three novel symmetrical ferrocenyl diphosphines with tertiary phosphorus atoms holding respectively nitrogen-containing heterocyclic derivatives of pyrrole, imidazole and benzazaphosphole were synthesized and characterized. Up to now, integration of heteroaromatic fragments, or more generally hetero-cycles, as substituents on the tertiary phosphines of symmetrical ferrocenyl diphosphines has been limited to the furyl motif. Their coordination to palladium and platinum group 10 transition metals was exemplified, and analyzed using single crystal X-ray diffraction. The performances obtained in palladium-catalyzed copper-free Sonogashira and Suzuki cross-coupling reactions using bromo…

Organic Chemistrychemistry.chemical_elementSonogashira couplingBiochemistryMedicinal chemistryCatalysisInorganic Chemistrychemistry.chemical_compoundchemistryTransition metalFerroceneDiphosphinesMaterials ChemistryOrganic chemistryImidazolePhysical and Theoretical ChemistryPalladiumPyrroleJournal of Organometallic Chemistry
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Converging and Diverging Synthetic Strategies to Tetradentate (N,N′)-Diaminomethyl,(P,P′)-Ferrocenyl Ligands: Influence of tert-Butyl Groups on Ferro…

2015

Hexasubstituted hybrid tetradentate (N,N′,P,P′)-ferrocenes bearing phosphino and aminomethyl groups, plus hindering tert-butyl moieties, were synthesized by using two different strategies: a “diverging” synthesis involving successive functionalization of preformed di-tert-butylated ferrocene and a “converging” assembly of the species from appropriately substituted cyclopentadienyl rings. While the new cyclopentadienyl salts formed are of interest, their assembly with iron dichloride used as a “converging” way to produce tetradentate ferrocene ligands presented several drawbacks. Conversely, the synthesis of new tert-butylated (aminomethyl)ferrocene derivatives was found convenient to furthe…

Tert butylchemistry.chemical_classificationStereochemistryArylOrganic ChemistryBackbone conformationInorganic Chemistrychemistry.chemical_compoundchemistryFerroceneCyclopentadienyl complexDiphosphinesSurface modificationPhysical and Theoretical ChemistryAlkylOrganometallics
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CCDC 1433505: Experimental Crystal Structure Determination

2015

Related Article: Fatima Allouch, Nejib Dwadnia, Nikolay V. Vologdin, Yurii V. Svyaschenko, Hélène Cattey, Marie-José Penouilh, Julien Roger, Daoud Naoufal, Ridha Ben Salem, Nadine Pirio, Jean-Cyrille Hierso|2015|Organometallics|34|5015|doi:10.1021/acs.organomet.5b00601

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersmeso-11'-bis(diphenylphosphino)-22'-bis((dimethylamino)methyl)ferroceneExperimental 3D Coordinates
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CCDC 922383: Experimental Crystal Structure Determination

2013

Related Article: Fatima Allouch, Nikolay V. Vologdin, Hélène Cattey, Nadine Pirio, Daoud Naoufal, Ali Kanj, Radomyr V. Smaliy, Aleksandr Savateev, Anatoly Marchenko, Anastasia Hurieva, Heorgii Koidan, Aleksandr N. Kostyuk, Jean-Cyrille Hierso|2013|J.Organomet.Chem.|735|38|doi:10.1016/j.jorganchem.2013.03.025

Space GroupCrystallographyCrystal SystemDichloro-(11'-bis(t-butyl(1-methylimidazol-2-yl)phosphino)ferrocene-PP')-palladium(ii) dichloromethane solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1433497: Experimental Crystal Structure Determination

2015

Related Article: Fatima Allouch, Nejib Dwadnia, Nikolay V. Vologdin, Yurii V. Svyaschenko, Hélène Cattey, Marie-José Penouilh, Julien Roger, Daoud Naoufal, Ridha Ben Salem, Nadine Pirio, Jean-Cyrille Hierso|2015|Organometallics|34|5015|doi:10.1021/acs.organomet.5b00601

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters11'-bis(diphenylphosphino)-22'-bis((diethylamino)methyl)ferroceneExperimental 3D Coordinates
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CCDC 1433499: Experimental Crystal Structure Determination

2015

Related Article: Fatima Allouch, Nejib Dwadnia, Nikolay V. Vologdin, Yurii V. Svyaschenko, Hélène Cattey, Marie-José Penouilh, Julien Roger, Daoud Naoufal, Ridha Ben Salem, Nadine Pirio, Jean-Cyrille Hierso|2015|Organometallics|34|5015|doi:10.1021/acs.organomet.5b00601

Space GroupCrystallography11'-bis(piperidin-1-ylmethyl)-33'-di-t-butylferroceneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 980179: Experimental Crystal Structure Determination

2014

Related Article: Nejib Dwadnia, Fatima Allouch, Nadine Pirio, Julien Roger, Hélène Cattey, Sophie Fournier, Marie-Josée Penouilh, Charles H. Devillers, Dominique Lucas, Daoud Naoufal, Ridha Ben Salem, and Jean-Cyrille Hierso|2013|Organometallics|32|5784|doi:10.1021/om400317s

Space GroupCrystallography11'-(((benzy)amino)dimethyl)ferroceneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 980175: Experimental Crystal Structure Determination

2014

Related Article: Nejib Dwadnia, Fatima Allouch, Nadine Pirio, Julien Roger, Hélène Cattey, Sophie Fournier, Marie-Josée Penouilh, Charles H. Devillers, Dominique Lucas, Daoud Naoufal, Ridha Ben Salem, and Jean-Cyrille Hierso|2013|Organometallics|32|5784|doi:10.1021/om400317s

Space GroupCrystallographyCrystal System11'-bis(piperidin-1-ylmethyl)ferroceneCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1433506: Experimental Crystal Structure Determination

2015

Related Article: Fatima Allouch, Nejib Dwadnia, Nikolay V. Vologdin, Yurii V. Svyaschenko, Hélène Cattey, Marie-José Penouilh, Julien Roger, Daoud Naoufal, Ridha Ben Salem, Nadine Pirio, Jean-Cyrille Hierso|2015|Organometallics|34|5015|doi:10.1021/acs.organomet.5b00601

Space GroupCrystallographyCrystal System1-(4-t-butyl-2-(diphenylphosphino)cyclopenta-24-dien-1-ylidene)-NN-dimethylmethanamineCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1433503: Experimental Crystal Structure Determination

2015

Related Article: Fatima Allouch, Nejib Dwadnia, Nikolay V. Vologdin, Yurii V. Svyaschenko, Hélène Cattey, Marie-José Penouilh, Julien Roger, Daoud Naoufal, Ridha Ben Salem, Nadine Pirio, Jean-Cyrille Hierso|2015|Organometallics|34|5015|doi:10.1021/acs.organomet.5b00601

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters44'-di-t-butyl-22'-bis(pyrrolidin-1-ylmethyl)-11'-bis(diphenylphosphino)ferrocene hydrateExperimental 3D Coordinates
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CCDC 1433501: Experimental Crystal Structure Determination

2015

Related Article: Fatima Allouch, Nejib Dwadnia, Nikolay V. Vologdin, Yurii V. Svyaschenko, Hélène Cattey, Marie-José Penouilh, Julien Roger, Daoud Naoufal, Ridha Ben Salem, Nadine Pirio, Jean-Cyrille Hierso|2015|Organometallics|34|5015|doi:10.1021/acs.organomet.5b00601

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters44'-di-t-butyl-22'-bis((diethylamino)methyl)-11'-bis(diphenylphosphino)ferroceneExperimental 3D Coordinates
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CCDC 1433498: Experimental Crystal Structure Determination

2015

Related Article: Fatima Allouch, Nejib Dwadnia, Nikolay V. Vologdin, Yurii V. Svyaschenko, Hélène Cattey, Marie-José Penouilh, Julien Roger, Daoud Naoufal, Ridha Ben Salem, Nadine Pirio, Jean-Cyrille Hierso|2015|Organometallics|34|5015|doi:10.1021/acs.organomet.5b00601

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersdichloro-(1'-((diethylammonio)methyl)-2-((diethylamino)methyl)-43'-di-t-buylferrocen-1-yl)-palladium(ii) dichloromethane solvateExperimental 3D Coordinates
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CCDC 1433504: Experimental Crystal Structure Determination

2015

Related Article: Fatima Allouch, Nejib Dwadnia, Nikolay V. Vologdin, Yurii V. Svyaschenko, Hélène Cattey, Marie-José Penouilh, Julien Roger, Daoud Naoufal, Ridha Ben Salem, Nadine Pirio, Jean-Cyrille Hierso|2015|Organometallics|34|5015|doi:10.1021/acs.organomet.5b00601

Space GroupCrystallographyCrystal SystemCrystal Structurerac-11'-bis(diphenylphosphino)-22'-bis((dimethylamino)methyl)ferroceneCell ParametersExperimental 3D Coordinates
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CCDC 980177: Experimental Crystal Structure Determination

2014

Related Article: Nejib Dwadnia, Fatima Allouch, Nadine Pirio, Julien Roger, Hélène Cattey, Sophie Fournier, Marie-Josée Penouilh, Charles H. Devillers, Dominique Lucas, Daoud Naoufal, Ridha Ben Salem, and Jean-Cyrille Hierso|2013|Organometallics|32|5784|doi:10.1021/om400317s

11'-(((4-phenyl-n-butyl)amino)dimethyl)ferroceneSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 922384: Experimental Crystal Structure Determination

2013

Related Article: Fatima Allouch, Nikolay V. Vologdin, Hélène Cattey, Nadine Pirio, Daoud Naoufal, Ali Kanj, Radomyr V. Smaliy, Aleksandr Savateev, Anatoly Marchenko, Anastasia Hurieva, Heorgii Koidan, Aleksandr N. Kostyuk, Jean-Cyrille Hierso|2013|J.Organomet.Chem.|735|38|doi:10.1016/j.jorganchem.2013.03.025

Space GroupCrystallographyCrystal SystemDichloro-(11'-bis(t-butyl(1-methylimidazol-2-yl)phosphino)ferrocene-PP')-palladium(ii) dichloromethane solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 980178: Experimental Crystal Structure Determination

2014

Related Article: Nejib Dwadnia, Fatima Allouch, Nadine Pirio, Julien Roger, Hélène Cattey, Sophie Fournier, Marie-Josée Penouilh, Charles H. Devillers, Dominique Lucas, Daoud Naoufal, Ridha Ben Salem, and Jean-Cyrille Hierso|2013|Organometallics|32|5784|doi:10.1021/om400317s

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates11'-(((n-butyl)amino)dimethyl)ferrocene
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CCDC 922386: Experimental Crystal Structure Determination

2013

Related Article: Fatima Allouch, Nikolay V. Vologdin, Hélène Cattey, Nadine Pirio, Daoud Naoufal, Ali Kanj, Radomyr V. Smaliy, Aleksandr Savateev, Anatoly Marchenko, Anastasia Hurieva, Heorgii Koidan, Aleksandr N. Kostyuk, Jean-Cyrille Hierso|2013|J.Organomet.Chem.|735|38|doi:10.1016/j.jorganchem.2013.03.025

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersDichloro-(11'-bis(NN5-trimethyl-3H-13-benzazaphosphol-2-amine-P)ferrocene-PP')-palladium(ii) chloroform solvateExperimental 3D Coordinates
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CCDC 980174: Experimental Crystal Structure Determination

2014

Related Article: Nejib Dwadnia, Fatima Allouch, Nadine Pirio, Julien Roger, Hélène Cattey, Sophie Fournier, Marie-Josée Penouilh, Charles H. Devillers, Dominique Lucas, Daoud Naoufal, Ridha Ben Salem, and Jean-Cyrille Hierso|2013|Organometallics|32|5784|doi:10.1021/om400317s

Space GroupCrystallographyCrystal SystemCrystal Structure11'-bis(pyrrolidin-1-ylmethyl)ferroceneCell ParametersExperimental 3D Coordinates
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CCDC 980176: Experimental Crystal Structure Determination

2014

Related Article: Nejib Dwadnia, Fatima Allouch, Nadine Pirio, Julien Roger, Hélène Cattey, Sophie Fournier, Marie-Josée Penouilh, Charles H. Devillers, Dominique Lucas, Daoud Naoufal, Ridha Ben Salem, and Jean-Cyrille Hierso|2013|Organometallics|32|5784|doi:10.1021/om400317s

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters11'-bis((dibenzylamino)methyl)ferroceneExperimental 3D Coordinates
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CCDC 1433502: Experimental Crystal Structure Determination

2015

Related Article: Fatima Allouch, Nejib Dwadnia, Nikolay V. Vologdin, Yurii V. Svyaschenko, Hélène Cattey, Marie-José Penouilh, Julien Roger, Daoud Naoufal, Ridha Ben Salem, Nadine Pirio, Jean-Cyrille Hierso|2015|Organometallics|34|5015|doi:10.1021/acs.organomet.5b00601

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters44'-di-t-butyl-22'-bis((diethylamino)methyl)-11'-bis(diphenylphosphino)ferroceneExperimental 3D Coordinates
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CCDC 922385: Experimental Crystal Structure Determination

2013

Related Article: Fatima Allouch, Nikolay V. Vologdin, Hélène Cattey, Nadine Pirio, Daoud Naoufal, Ali Kanj, Radomyr V. Smaliy, Aleksandr Savateev, Anatoly Marchenko, Anastasia Hurieva, Heorgii Koidan, Aleksandr N. Kostyuk, Jean-Cyrille Hierso|2013|J.Organomet.Chem.|735|38|doi:10.1016/j.jorganchem.2013.03.025

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersDichloro-(11'-bis(t-butyl(1-methylimidazol-2-yl)phosphino)ferrocene-PP')-platinum dichloromethane solvateExperimental 3D Coordinates
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CCDC 1433500: Experimental Crystal Structure Determination

2015

Related Article: Fatima Allouch, Nejib Dwadnia, Nikolay V. Vologdin, Yurii V. Svyaschenko, Hélène Cattey, Marie-José Penouilh, Julien Roger, Daoud Naoufal, Ridha Ben Salem, Nadine Pirio, Jean-Cyrille Hierso|2015|Organometallics|34|5015|doi:10.1021/acs.organomet.5b00601

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters11'-bis((dibenzylamino)methyl)-33'-di-t-butylferroceneExperimental 3D Coordinates
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CCDC 1433507: Experimental Crystal Structure Determination

2015

Related Article: Fatima Allouch, Nejib Dwadnia, Nikolay V. Vologdin, Yurii V. Svyaschenko, Hélène Cattey, Marie-José Penouilh, Julien Roger, Daoud Naoufal, Ridha Ben Salem, Nadine Pirio, Jean-Cyrille Hierso|2015|Organometallics|34|5015|doi:10.1021/acs.organomet.5b00601

Space GroupCrystallography44'-di-t-butyl-22'-bis((dimethylamino)methyl)-11'-bis(diphenylphosphino)ferroceneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 980180: Experimental Crystal Structure Determination

2014

Related Article: Nejib Dwadnia, Fatima Allouch, Nadine Pirio, Julien Roger, Hélène Cattey, Sophie Fournier, Marie-Josée Penouilh, Charles H. Devillers, Dominique Lucas, Daoud Naoufal, Ridha Ben Salem, and Jean-Cyrille Hierso|2013|Organometallics|32|5784|doi:10.1021/om400317s

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters11'-bis((t-butylamino)methyl)ferroceneExperimental 3D Coordinates
researchProduct

CCDC 980181: Experimental Crystal Structure Determination

2014

Related Article: Nejib Dwadnia, Fatima Allouch, Nadine Pirio, Julien Roger, Hélène Cattey, Sophie Fournier, Marie-Josée Penouilh, Charles H. Devillers, Dominique Lucas, Daoud Naoufal, Ridha Ben Salem, and Jean-Cyrille Hierso|2013|Organometallics|32|5784|doi:10.1021/om400317s

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters11-(mu~2~-(n-butylamino)dimethyl)-diferroceneExperimental 3D Coordinates
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CCDC 1433508: Experimental Crystal Structure Determination

2015

Related Article: Fatima Allouch, Nejib Dwadnia, Nikolay V. Vologdin, Yurii V. Svyaschenko, Hélène Cattey, Marie-José Penouilh, Julien Roger, Daoud Naoufal, Ridha Ben Salem, Nadine Pirio, Jean-Cyrille Hierso|2015|Organometallics|34|5015|doi:10.1021/acs.organomet.5b00601

Space GroupCrystallography33'-di-t-butyl-11'-bis(pyrrolidin-1-ylmethyl)ferroceneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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