Sulfur’s role in the flame retardancy of thio-ether–linked hyperbranched polyphosphoesters in epoxy resins
Abstract Hyperbranched polyphosphoesters are promising multifunctional flame retardants for epoxy resins. These polymers were prepared via thiol-ene polyaddition reactions. While key chemical transformations and modes of actions were elucidated, the role of sulfur in the chemical composition remains an open question. In this study, the FR-performance of a series of phosphorus-based flame retardant additives with and without sulfur (thio-ethers or sulfones) in their structure are compared. The successful synthesis of thio-ether or sulfone-containing variants is described and verified by 1H and 31P NMR, also FTIR and MALDI-TOF. A decomposition process is proposed from pyrolytic evolved gas an…
Measurement of the branching fraction of the decay Bs0→KS0KS0
A measurement of the branching fraction of the decay Bs0→KS0KS0 is performed using proton-proton collision data corresponding to an integrated luminosity of 5 fb-1 collected by the LHCb experiment between 2011 and 2016. The branching fraction is determined to be B(Bs0→KS0KS0)=[8.3±1.6(stat)±0.9(syst)±0.8(norm)±0.3(fs/fd)]×10-6, where the first uncertainty is statistical, the second is systematic, and the third and fourth are due to uncertainties on the branching fraction of the normalization mode B0→φKS0 and the ratio of hadronization fractions fs/fd. This is the most precise measurement of this branching fraction to date. Furthermore, a measurement of the branching fraction of the decay B0…
Measurement of the W boson mass
The W boson mass is measured using proton-proton collision data at root s = 13 TeV corresponding to an integrated luminosity of 1.7fb(-1) recorded during 2016 by the LHCb experiment. With a simultaneous fit of the muon q/p(T) distribution of a sample of W ->mu y decays and the phi* distribution of a sample of Z -> mu mu decays the W boson mass is determined to be