0000000000824178
AUTHOR
Gonela Vijay Kumar
New symmetrical dinucleating ligand based assembly of bridged dicopper(II) and dizinc(II) centers: Synthesis, structure, spectroscopy, magnetic properties and glycoside hydrolysis
Two dinuclear copper(II) complexes Li(H2O)(3)(CH3OH)](4)Cu2Br4]Cu-2(cpdp)(mu-O2CCH3)](4)(OH)(2) (1), Cu (H2O)(4)]Cu-2(cpdp)(mu-O2CC6H5)](2)Cl-2 center dot 5H(2)O (2), and a dinuclear zinc(II) complex Zn-2(cpdp)(mu-O2CCH3)] (3) have been synthesized using pyridine and benzoate functionality based new symmetrical dinucleating ligand, N, N'-Bis2-carboxybenzomethyl]-N, N'-Bis2-pyridylmethyl]-1,3-diaminopropan-2-ol (H(3)cpdp). Complexes 1, 2 and 3 have been synthesized by carrying out reaction of the ligand H3cpdp with stoichiometric amounts of Cu-2(O2CCH3)(4)(H2O)(2)], CuCl2 center dot 2H(2)O/C6H5COONa, and Zn(CH3COO)(2)center dot 2H(2)O, respectively, in methanol in the presence of NaOH at amb…
CCDC 1033416: Experimental Crystal Structure Determination
Related Article: Ayan Patra, Shobhraj Haldar, Gonela Vijay Kumar, Luca Carrella, Aloke Kumar Ghosh, Manindranath Bera|2015|Inorg.Chim.Acta|436|195|doi:10.1016/j.ica.2015.07.039
CCDC 1033417: Experimental Crystal Structure Determination
Related Article: Ayan Patra, Shobhraj Haldar, Gonela Vijay Kumar, Luca Carrella, Aloke Kumar Ghosh, Manindranath Bera|2015|Inorg.Chim.Acta|436|195|doi:10.1016/j.ica.2015.07.039