0000000000842987
AUTHOR
Katie L. M. Harriman
A Luminescent Thermometer Exhibiting Slow Relaxation of the Magnetization: Toward Self-Monitored Building Blocks for Next-Generation Optomagnetic Devices
The development and integration of Single-Molecule Magnets (SMMs) into molecular electronic devices continue to be an exciting challenge. In such potential devices, heat generation due to the electric current is a critical issue that has to be considered upon device fabrication. To read out accurately the temperature at the submicrometer spatial range, new multifunctional SMMs need to be developed. Herein, we present the first self-calibrated molecular thermometer with SMM properties, which provides an elegant avenue to address these issues. The employment of 2,2′-bipyrimidine and 1,1,1-trifluoroacetylacetonate ligands results in a dinuclear compound, [Dy2(bpm)(tfaa)6], which exhibits slow …
CCDC 1859276: Experimental Crystal Structure Determination
Related Article: Dylan Errulat, Riccardo Marin, Diogo A. Gálico, Katie L. M. Harriman, Amelie Pialat, Bulat Gabidullin, Fernando Iikawa, Odilon D. D. Couto, Jani O. Moilanen, Eva Hemmer, Fernando A. Sigoli, Muralee Murugesu|2019|ACS Cent.Sci.|5|1187|doi:10.1021/acscentsci.9b00288
CCDC 1859277: Experimental Crystal Structure Determination
Related Article: Dylan Errulat, Riccardo Marin, Diogo A. Gálico, Katie L. M. Harriman, Amelie Pialat, Bulat Gabidullin, Fernando Iikawa, Odilon D. D. Couto, Jani O. Moilanen, Eva Hemmer, Fernando A. Sigoli, Muralee Murugesu|2019|ACS Cent.Sci.|5|1187|doi:10.1021/acscentsci.9b00288