The effect of feedstock origin and temperature on the structure and reactivity of char from pyrolysis at 1300–2800 °C
This study reports the effect of feedstock origin, residence time, and heat treatment temperature on CO2 and O2 reactivities, nanostructure and carbon chemistry of chars prepared at 1300, 1600, 2400, and 2800 °C in a slow pyrolysis reactor. The structure of char was characterized by transmission electron microscopy and Raman spectroscopy. The CO2 and O2 reactivity of char was investigated by thermogravimetric analysis. Results showed that the ash composition and residence time influence the char reactivity less than the heat treatment temperature. The heat treatment temperature and co-pyrolysis of pinewood char with biooil decreased the CO2 reactivity, approaching that of metallurgical coke…
Characterization and reactivity of charcoal from high temperature pyrolysis (800-1600°C)
This study presents the effect of wood origin and heat treatment temperature on the CO2 reactivity, nanostructure and carbon chemistry of chars prepared at 800, 1200, and 1600 °C in slow pyrolysis reactors. The structure of charcoal was characterized by transmission electron microscopy, Raman spectroscopy, mercury intrusion porosimetry and N2 adsorption. The CO2 reactivity of char was investigated by thermogravimetric analysis. Results showed that spruce and oak chars have similar reactivity at all heat treatment temperatures. The oak char prepared at 1600 °C contained long and flat graphene layers and interplanar distance that is similar to graphite and thus, was more ordered t…