Relaxation phenomena in mixed isomeric alcohols by Mandelstam-Brillouin scattering

1991

Mandelstam-Brillouin scattering data in mixed isomeric alcohols n-pentanol (nPe-OH) and 2-methyl-2-butanol (2Me-2BuOH) are presented. The hypersonic velocity and normalized absorption are measured as a function of the scattering angle, in the temperature range from - 15-degrees-C to + 45-degrees-C, and as a function of n-PeOH molar fraction going from the pure n-PeOH to the pure 2Me-2BuOH. The experimental results confirm the existence of a shear relaxation phenomenon in the GHz region, that has been previously detected in pure liquids. The temperature dependence of the relaxation time tau-s and of the shear modulus G-infinity evaluated within viscoelastic liquid models, support the existen…