Shifts of the 3D - 4P transitions in different isotopes of positive calcium ions

A sample of stable isotopes containing the masses 40, 42, 43 and 44 was stored under buffer-gas conditions in a Paul ion trap. After population of the metastable 3D levels by spontaneous decay of the laser-excited 4P state we observed laser-induced fluorescence when we scanned a laser across the different 3D - 4P fine-structure lines at 850, 854 and 866 nm. From the Doppler-limited lines of these transitions we deduced the isotope shifts, which are of the order of several GHz due to the large specific mass shift of the metastable 3D levels.