0000000000877479
AUTHOR
Vitaly V. Pavlishchuk
Combination of single-molecule magnet behaviour and luminescence properties in a new series of lanthanide complexes with tris(pyrazolyl)borate and oligo(β-diketonate) ligands.
A series of tris(pyrazolyl)borate mono-, di- and trinuclear complexes, [Tp2Ln]nX (Ln = Eu, Tb, Gd, Dy, Xn− = various mono-, bis- and tris(β-diketonates) has been prepared. The Tb3+ and Dy3+ complexes are luminescent single molecular magnets (SMM) and exhibit luminescence quantum efficiencies up to 73% for the Tb3+ and 4.4% for the Dy3+ compounds. Similar Eu3+ complexes display bright emission only at lower temperatures. The Dy3+ and Tb3+ complexes possess SMM behavior in a non-zero dc field at low temperatures, while the polynuclear Dy3+ complexes also show slow magnetic relaxation even in zero dc field up to 8 K. Ueff-values determined from dynamic magnetic measurements were up to 31 and 6…
A Tetrameric Nickel(II) “Chair” with both Antiferromagnetic Internal Coupling and Ferromagnetic Spin Alignment
Structural, magnetic and related attributes of some oximate-bridged tetranuclear nickel(ii) rhombs and a dinuclear congenerElectronic supplementary information (ESI) available: mass spectra, χT vs. T, response of magnetic properties, low-lying spin levels and UV-VIS data. See http://www.rsc.org/suppdata/dt/b3/b300539a/
New oximate-bridged tetranuclear nickel(II) complexes of compositions {Ni(Dien)}2(μ3-OH)2{Ni2(Moda)4}(ClO4)2·Solv (Solv = H2O, 1a; Solv = 2CH3NO2, 1b; Solv = 2H2O·2C4H8O2, 1c), {Ni(Sdien)}2(μ3-OH)2{Ni2(Moda)4}(ClO4)2·H2O (2), {Ni(Odien)}2(μ3-OH)2{Ni2(Moda)4}(ClO4)2·0.6H2O (3), {Ni(Dien)}2(μ3-OH)2{Ni2(Inaf)4}(ClO4)2·CH3NO2 (4) and {Ni(Odien)}2(μ3-OH)2{Ni2(Inaf)4}(ClO4)2·2NaClO4·2H2O (5) and the dinuclear complex (Ni{Odien})2(Moda)2(ClO4)2 (6) have been prepared (Dien = 1,5-diamino-3-azapentane, Odien = 1,5-diamino-3-oxapentane, Sdien = 1,5-diamino-3-thiapentane, ModaH = butane-2,3-dione monooxime, InafH = phenylglyoxaldoxime). X-ray examination revealed similar structures for 1a, 1b, 1c, 2 a…
Synthesis, structure and magnetic properties of oligometallic systems derived from di- and trinuclear copper(ii) amido-oximate complexes
Three heterometallic complexes [M(H(2)O)(n)][Cu(3)L(2)(H(2)O)] (M = Mn(2+), Co(2+) or Ba(2+)) and one dinuclear compound (CuDien)(CuL{H(2)O}) were prepared by interaction of anionic compounds Cu(3)L(2)(2-) or CuL(2-) with the corresponding cations (H(4)L = 1,9-dicyano-1,9-bis(hydroximino)-3,7-diazanonane-2,8-dione; Dien = 1,5-diamino-3-azapentane). The complexes [M(H(2)O)(n)][Cu(3)L(2)(H(2)O)] have a polymeric structure, formed via oligomerization of Cu(3)L(2)(2-) units and additionally, in the case of the Ba-salt, by binding of Cu(3)L(2)(2-) units through Ba(2+). Antiferromagnetic interactions occur in all the complexes, while for [Co(H(2)O)(6)][Cu(3)L(2)(H(2)O)] there is evidence of some …
CCDC 1979793: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979785: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979783: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979777: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979787: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979786: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979788: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979789: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979781: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979776: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979790: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979782: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979775: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979780: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979791: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979794: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979778: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979784: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979779: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A
CCDC 1979792: Experimental Crystal Structure Determination
Related Article: Elena A. Mikhalyova, Matthias Zeller, Jerry P. Jasinski, Raymond J. Butcher, Luca M. Carrella, Alexander E. Sedykh, Konstantin S. Gavrilenko, Sergey S. Smola, Michael Frasso, Sebastian Calderon Cazorla, Kuluni Perera, Anni Shi, Habib G. Ranjbar, Casey Smith, Alexandru Deac, Youlin Liu, Sean M. McGee, Vladimir P. Dotsenko, Michael U. Kumke, Klaus Müller-Buschbaum, Eva Rentschler, Anthony W. Addison, Vitaly V. Pavlishchuk|2020|Dalton Trans.|49|7774|doi:10.1039/D0DT00600A