Three Co(II) Metal-Organic Frameworks with Diverse Architectures for Selective Gas Sorption and Magnetic Studies.
Three Co(II) metal–organic frameworks, namely, {[Co2(L)2(OBA)2(H2O)4]·xG}n (1), {[Co(L)0.5(OBA)]·xG}n (2), and {[Co2(L)2(OBA)2(H2O)]·DMA·xG}n (3) [where L = 2,5-bis(3-pyridyl)-3,4-diaza-2,4-hexadiene, H2OBA = 4,4′-oxybisbenzoic acid, DMF = dimethylformamide, DMA = dimethylacetamide, and G denotes disordered guest molecules], have been synthesized under diverse reaction conditions through self-assembly of a bent dicarboxylate and a linear spacer with a Co(II) ion. While 1 is crystallized at room temperature in DMF to form a 2D layer structure, 2 is formed by the assembly of similar components under solvothermal conditions with a 3D network structure. On the other hand, changing the solvent t…
CCDC 1896306: Experimental Crystal Structure Determination
Related Article: Arun Pal, Santanu Chand, Joan Cano Boquera, Francesc Lloret, Jian-Bin Lin, Shyam Chand Pal, Madhab C. Das|2019|Inorg.Chem.|58|6246|doi:10.1021/acs.inorgchem.9b00471
CCDC 1896307: Experimental Crystal Structure Determination
Related Article: Arun Pal, Santanu Chand, Joan Cano Boquera, Francesc Lloret, Jian-Bin Lin, Shyam Chand Pal, Madhab C. Das|2019|Inorg.Chem.|58|6246|doi:10.1021/acs.inorgchem.9b00471
CCDC 1896308: Experimental Crystal Structure Determination
Related Article: Arun Pal, Santanu Chand, Joan Cano Boquera, Francesc Lloret, Jian-Bin Lin, Shyam Chand Pal, Madhab C. Das|2019|Inorg.Chem.|58|6246|doi:10.1021/acs.inorgchem.9b00471