Author: Yunhui Dong

0000000000885203

AUTHOR

Yunhui Dong

Unconventional dihydrogen-bond interaction induced cyanide-bridged chiral nano-sized magnetic molecular wheel: synthesis, crystal structure and systematic theoretical magnetism investigation

A pair of cyanide-bridged 4d–3d heterobimetallic chiral macrocyclic enantiomeric magnetic complexes have been successfully assembled from the trans-dicyanoruthenium(III) building block [PPh4][Ru(Salen)(CN)2] (Salen = N,N-ethylenebis(salicylideneaminato)dianion) and [Mn((S,S/R,R)-Salcy)(H2O)2]ClO4 (Salcy = N,N′-(1,2-cyclohexanediylethylene)bis(salicylideneiminato)dianion) with the great help of the dihydrogen bond (DHB) interaction and characterized by elemental analysis, IR spectroscopy, circular dichroism (CD) and magnetic circular dichroism (MCD) spectroscopy. Single X-ray diffraction reveals that complex 1, {[Ru(Salen)(CN)2][R,R-Mn(Salcy)]}6·PPh3·6CH3CN·6CH3OH·12H2O, is a neutral dodecan…

research product

CCDC 1872883: Experimental Crystal Structure Determination

Related Article: Daopeng Zhang, Joan Cano, Wenlong Lan, Hui Liu, Fenggang Sun, Yunhui Dong, Zhen Zhou, Lu Yang, Qingyun Liu, Jianzhuang Jiang|2019|J.Mater.Chem.C|7|3623|doi:10.1039/C8TC05650A

research product

PEPhysical Sciences and Engineering
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