0000000000887038

AUTHOR

Cunbin An

0000-0001-6019-2700

showing 3 related works from this author

Layered Thiadiazoloquinoxaline-Containing Long Pyrene-Fused N-Heteroacenes

2018

Three thiadiazoloquinoxaline-containing long pyrene-fused N-heteroacenes with 8, 13, and 18 rings were designed and synthesized. They show high electron affinities (EAs) of approximately 4.1 eV, which were derived from the onset of the reduction peaks in cyclic voltammetry. Crystal structure analysis revealed in-plane extension through close contacts between thiadiazole units as well as layered packing, enabling in-plane and interlayer electron transport. Organic field-effect transistor devices provided electron mobilities, which suggest a potential way to enhance the charge transport in long N-heteroacenes.

Materials science010405 organic chemistryTransistorGeneral MedicineGeneral ChemistryElectronCrystal structure010402 general chemistry01 natural sciencesElectron transport chainAffinitiesCatalysis0104 chemical scienceslaw.inventionCrystallographychemistry.chemical_compoundchemistrylawPyreneCyclic voltammetryHigh electronAngewandte Chemie International Edition
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CCDC 1816642: Experimental Crystal Structure Determination

2018

Related Article: Ben-Lin, Hu Ke Zhang, Cunbin An, Dieter Schollmeyer, Wojciech Pisula, Martin Baumgarten|2018|Angew.Chem.,Int.Ed.|57|12375|doi:10.1002/anie.201803230

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters259121519-hexakis{[triisopropylsilyl]ethynyl}[125]thiadiazolo[34-i][125]thiadiazolo[3''4'':6'7']quinoxalino[2'3':910]phenanthro[45-abc]phenazineExperimental 3D Coordinates
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CCDC 1816643: Experimental Crystal Structure Determination

2018

Related Article: Ben-Lin, Hu Ke Zhang, Cunbin An, Dieter Schollmeyer, Wojciech Pisula, Martin Baumgarten|2018|Angew.Chem.,Int.Ed.|57|12375|doi:10.1002/anie.201803230

Space GroupCrystallography1117232941475359-octakis((2-[triisopropylsilyl]ethynyl))-2050-dithia-3715192125333745495155-dodecaazaheptadecacyclo[37.21.2.2927.0238.0436.0634.0832.01426.01624.01822.04362.04456.04654.04852.05761.01364.03163]tetrahexaconta-1(61)246(34)79(64)1012141618212325272931(63)32353739(62)40424446485153555759-hentriacontaene tetrahydrofuran solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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