A tris-oxovanadium pyrogallate complex: synthesis, structure, and magnetic and electronic properties
International audience; With the aim of identifying new cation-phenolate complexes, we herein investigated the reactivity of pyrogallol (H(3)pgal) with vanadium salts. A trimetallic anionic complex was identified, and found to be formed under a broad set of reaction conditions. This complex, with the formula V3O3(pgal)(3)(3-), consists of three oxovanadium(iv) units connected together by three pyrogallate ligands to afford a bowl-shaped species presenting a pseudo 3-fold symmetry axis. Its crystal structure is reported, as well as its characterisation by a broad set of techniques, including powder X-ray diffraction, thermogravimetric analysis, infrared and Raman spectroscopy, and solid stat…
CCDC 2087735: Experimental Crystal Structure Determination
Related Article: Hassan Mkhadder, Morgane Denis, Mónica Giménez-Marqués, Walter Cañón-Mancisidor, Bernard Humbert, Elise Deunf, Philippe Poizot, Thomas Devic|2021|Dalton Trans.|50|13399|doi:10.1039/D1DT01990B
CCDC 2087736: Experimental Crystal Structure Determination
Related Article: Hassan Mkhadder, Morgane Denis, Mónica Giménez-Marqués, Walter Cañón-Mancisidor, Bernard Humbert, Elise Deunf, Philippe Poizot, Thomas Devic|2021|Dalton Trans.|50|13399|doi:10.1039/D1DT01990B