Author: Muni Rathnam

0000000000909385

AUTHOR

Muni Rathnam

showing 3 related works from this author

Discrete unusual mixed-bridged trinuclear CoIII2CoII and pentanuclear NiII coordination complexes supported by a phenolate-based ligand: theoretical …

2021

Two new complexes [CoIII2CoII(μ-OL)2(μ-OOCCH3)2(μ-N3)2(N3)2]·Et2O (1·Et2O) and [NiII5(μ-OL)4(μ-OOCCH3)2(OOCCH3)2(μ-N3)2]·CH3CN (2) (HOL = 2-((2-(pyridin-2-yl)ethylamino)methyl)phenol) have been synthesized and characterized by elemental analysis, IR, and UV/Vis spectroscopy. Structural analysis revealed that 1 is a discrete trinuclear and 2 is a discrete pentanuclear coordination complex. In complex 1, terminal metal (CoIII) is in a distorted octahedral MN4O2 environment where coordination is satisfied by two nitrogen atoms and one oxygen atom of the ligand, and an oxygen atom from the acetate group and two nitrogen atoms from azide (one each from the bridging and terminal ones). The centra…

chemistry.chemical_classificationLigandGeneral ChemistryCrystal structureMagnetic susceptibilityCatalysisCoordination complexchemistry.chemical_compoundCrystallographychemistryOctahedronPyridineMaterials ChemistryAntiferromagnetismAzideNew Journal of Chemistry

researchProduct

CCDC 2046943: Experimental Crystal Structure Determination

2021

Related Article: Richa, Muni Rathnam, Akhilesh Kumar, Indresh Verma, Julia Kłak, Joan Cano, Antonio J. Mota, Amit Rajput, Himanshu Arora|2021|New J.Chem.|45|6053|doi:10.1039/D1NJ00228G

Space GroupCrystallographyCrystal SystemCrystal Structurebis(mu-acetato)-bis(mu-azido)-bis(mu-2-({[2-(pyridin-2-yl)ethyl]amino}methyl)phenolato)-diazido-tri-cobalt diethyl ether solvateCell ParametersExperimental 3D Coordinates

researchProduct

CCDC 2046942: Experimental Crystal Structure Determination

2021

Related Article: Richa, Muni Rathnam, Akhilesh Kumar, Indresh Verma, Julia Kłak, Joan Cano, Antonio J. Mota, Amit Rajput, Himanshu Arora|2021|New J.Chem.|45|6053|doi:10.1039/D1NJ00228G

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-acetato)-bis(mu-azido)-tetrakis(mu-2-({[2-(pyridin-2-yl)ethyl]amino}methyl)phenolato)-bis(acetato)-penta-nickel acetonitrile solvateExperimental 3D Coordinates

researchProduct

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