0000000000918782

AUTHOR

Sattwick Halder

showing 2 related works from this author

Synthesis and characterization of a novel dicyanamide-bridged Co(II) 1-D coordination polymer with a N 4 -donor Schiff base ligand

2017

The synthesis, structure and magnetic properties of a novel Co(II) 1D coordination polymer, [Co(L)(µ1,5-dca)(ClO4)2·MeOH]n (1) are described. Compound 1 contains two independent cationic Co(II) chains (CoA and CoB) which are parallel to the c direction and present short π-π and C-H⋯π interactions with two neighbouring chains along the b direction, giving rise to alternating layers of chains A and B in the bc plane. Variable-temperature magnetic susceptibility measurements shows a weak antiferromagnetic coupling among the adjacent cobalt(II) centres mediated through μ1,5-dca− bridge.

Schiff base010405 organic chemistryChemistryStereochemistryLigandCoordination polymerCationic polymerizationchemistry.chemical_element010402 general chemistry01 natural sciencesMagnetic susceptibilityAntiferromagnetic coupling0104 chemical sciencesInorganic ChemistryCrystallographychemistry.chemical_compoundMaterials ChemistryPhysical and Theoretical ChemistryCobaltDicyanamideInorganica Chimica Acta
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CCDC 1478367: Experimental Crystal Structure Determination

2017

Related Article: Saikat Banerjee, Sattwick Halder, Paula Brandão, Carlos J. Gómez García, Samia Benmansour, Amrita Saha|2017|Inorg.Chim.Acta|464|65|doi:10.1016/j.ica.2017.04.056

catena-[(mu-dicyanoazanide)-(NN'-(22-dimethylpropane-13-diyl)bis(1-(pyridin-2-yl)methanimine))-cobalt(ii) perchlorate methanol solvate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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