Magnetic Properties of a New Hexahalorhenate(IV) Compound and Structural Comparison with Its Hexahaloplatinate(IV) Analog
Metal Doping of Au25(SR)18- Clusters : Insights and Hindsights
The structure, properties, and applications of atomically precise gold nanoclusters are the object of active research worldwide. Over the last few years, research has been also focusing on selective doping of metal nanoclusters through introduction of foreign-metal atoms. Doping has been studied for several clusters, especially the atomically precise Au25(SR)18. Doping has been carried out with noble metals, such as platinum, and less noble metals, such as cadmium and mercury, also because of the ease by which monodoping can be achieved with these metals. Previous studies, which relied extensively on the use of mass spectrometry and single crystal X-ray crystallography, led to assign the sp…
Five-coordinate complexes of palladium(ii) and platinum(ii) with α-diimine and 1,5-cyclooctadiene ligands
The five-coordinate complexes [PtMe(cod)(N–N′)]BF4 [cod = η2,η2-cyclooctadiene, N–N′ = (6-R2)C5H3N-2-CHNR1 (R1 = C6H4OMe-4, R2 = H (1), Me (2); R1 = CMe3, R2 = H (3), Me (4); R1 = (R)-bornyl, R2 = Me (5))] are readily obtained from the reaction of [PtClMe(cod)] with N–N′ in the presence of NaBF4. The preparation of [PtMe(cod)(6)]BF4 (6 = 4-MeOC6H4NCHCHNC6H4OMe-4), [PdMe(cod)(N–N′)]BF4 and [PtCl(cod)(N–N′)]BF4 (N–N′ = 2, 4) requires chloride abstraction by AgBF4 from [PtClMe(cod)], [PdClMe(cod)] and [PtCl2(cod)], respectively, followed by coordination of N–N′. The NMR spectral data suggest a trigonal-bipyramidal structure with chelating cod and N–N′ ligands, where the α-diimine and one CC bo…
CCDC 1938197: Experimental Crystal Structure Determination
Related Article: Wenwen Fei, Sabrina Antonello, Tiziano Dainese, Alessandro Dolmella, Manu Lahtinen, Kari Rissanen, Alfonso Venzo, Flavio Maran|2019|J.Am.Chem.Soc.|141|16033|doi:10.1021/jacs.9b08228
CCDC 1938194: Experimental Crystal Structure Determination
Related Article: Wenwen Fei, Sabrina Antonello, Tiziano Dainese, Alessandro Dolmella, Manu Lahtinen, Kari Rissanen, Alfonso Venzo, Flavio Maran|2019|J.Am.Chem.Soc.|141|16033|doi:10.1021/jacs.9b08228
CCDC 1938193: Experimental Crystal Structure Determination
Related Article: Wenwen Fei, Sabrina Antonello, Tiziano Dainese, Alessandro Dolmella, Manu Lahtinen, Kari Rissanen, Alfonso Venzo, Flavio Maran|2019|J.Am.Chem.Soc.|141|16033|doi:10.1021/jacs.9b08228
CCDC 1938198: Experimental Crystal Structure Determination
Related Article: Wenwen Fei, Sabrina Antonello, Tiziano Dainese, Alessandro Dolmella, Manu Lahtinen, Kari Rissanen, Alfonso Venzo, Flavio Maran|2019|J.Am.Chem.Soc.|141|16033|doi:10.1021/jacs.9b08228
CCDC 1983533: Experimental Crystal Structure Determination
Related Article: Fabio Piccinelli, Marco Bettinelli, Joan Cano, Francesc Lloret, Miguel Julve, Alessandro Dolmella|2020|Eur.J.Inorg.Chem.|2020|2246|doi:10.1002/ejic.202000199
CCDC 1938195: Experimental Crystal Structure Determination
Related Article: Wenwen Fei, Sabrina Antonello, Tiziano Dainese, Alessandro Dolmella, Manu Lahtinen, Kari Rissanen, Alfonso Venzo, Flavio Maran|2019|J.Am.Chem.Soc.|141|16033|doi:10.1021/jacs.9b08228
CCDC 1983534: Experimental Crystal Structure Determination
Related Article: Fabio Piccinelli, Marco Bettinelli, Joan Cano, Francesc Lloret, Miguel Julve, Alessandro Dolmella|2020|Eur.J.Inorg.Chem.|2020|2246|doi:10.1002/ejic.202000199
CCDC 1938196: Experimental Crystal Structure Determination
Related Article: Wenwen Fei, Sabrina Antonello, Tiziano Dainese, Alessandro Dolmella, Manu Lahtinen, Kari Rissanen, Alfonso Venzo, Flavio Maran|2019|J.Am.Chem.Soc.|141|16033|doi:10.1021/jacs.9b08228
CCDC 1938192: Experimental Crystal Structure Determination
Related Article: Wenwen Fei, Sabrina Antonello, Tiziano Dainese, Alessandro Dolmella, Manu Lahtinen, Kari Rissanen, Alfonso Venzo, Flavio Maran|2019|J.Am.Chem.Soc.|141|16033|doi:10.1021/jacs.9b08228