High Resolution Study of the v1 + 2v2 −v2 and 2v2 + v3 − v2 ”Hot” Bands and Ro-Vibrational Re-Analysis of the v1 + v2/v2 + v3/3v3 Poliad of the SO2 Molecule

The main goal of the present study was to analyse rotational stuctures of two excited vibrational states, (120) and (021). Because both the band, v1+2v2 and 2v2+v3 one are extremally weak, a special efforts were faired to record very weak hot bands, v1+2v2−v2 and 2v2+v3−v2.Both of those bands are located in the region of considerably more stronger combinational bands, v1 + v2 and v2 + v3. On that reason, as the first step of analysis, we made assignments of transitions belonging to these v1 + v2 and v2 + v3 bands. As the result of analysis, we were able to assign three times more transitions to the bands v1 + v2 and v2 + v3 than it was known in the before literature. After "cleaning" the ex…

High resolution study of the SO2 infrared spectra: calculation scheme for assignment of transitions in very weak ro-vibrational bands.