Geochemistry and isotope composition (Sr, Pb, δ66Zn) of Vulcano fumaroles (Aeolian Islands, Italy)

We present and discuss temperatures, major and trace element gas geochemistry, radiogenic isotopes (Pb, Sr) and the first Zn isotope data of fumarole condensates and altered rocks from the Vulcano fumarolic field. The fumaroles of the La Fossa cone, sampled on 5th May 2015, have temperatures ranging between 233 and 427 °C. They plot compositionally on the mixing trend between the magmatic and hydrothermal end-members defined by previous studies, but are strongly displaced towards the hydrothermal component. Correlations of radiogenic (Sr, Pb) and stable isotopes of Zn with δ13CCO2 and several trace elements of the fumarolic acid condensates support mixing between the above mentioned distinc…