Optical investigation of spin-crossover in cobalt(II) bis-terpy complexes

2007

Abstract The spin transition of the [Co(terpy) 2 ] 2+ complex (terpy = 2,2′:6′,2″-terpyridine) is analysed based on experimental data from optical spectroscopy and magnetic susceptibility measurements. The single crystal absorption spectrum of [Co(terpy) 2 ](ClO 4 ) 2 shows an asymmetric absorption band at 14 400 cm −1 with an intensity typical for a spin-allowed d–d transition and a temperature behaviour typical for a thermal spin transition. The single crystal absorption spectra of suggest that in this compound, the complex is essentially in the high-spin state at all temperatures. However, the increase in intensity observed in the region of the low-spin MLCT transition with increasing te…