0000000000930142

AUTHOR

Paolo Conti

showing 4 related works from this author

Newly discovered orichalcum ingots from Mediterranean sea: Further investigation

2021

Abstract In February 2016, 47 ingots were found in the seabed of Contrada Bulala (Gela, CL, Italy) near the site where 40 ingots had previously been recovered. The ingots composition was determined to be a Cu - Zn alloy, dated by the archaeologist to the VI century B.C. This specific alloy was then known as Orichalcum. From an archaeological point of view, the first question raised about the new discovery was whether the ingots of the first and the second excavations belonged to the same shipwreck. Following the previous study, an elemental analysis was performed on the ingots from the second finding by using ICP-OS and ICP-MS techniques. The chemometric treatment of the analytical results …

ArcheologyMediterranean seaChemometric approach ICP-MS ICP-OES Lead Isotopic ratio Orichalcum ingotsExcavationArchaeologyGeologySettore CHIM/02 - Chimica Fisica
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Synthesis and Characterization of Nanostructured Cobalt Hexacyanoferrate

2010

Cobalt hexacyanoferrate (CoHCF) nanoparticles have been synthesized by mixing aqueous solutions of K3Fe(CN)6 and CoCl2 under vigorous stirring at different temperatures and following two different procedures, drop-by-drop or immediate mixing. The resulting CoHCF nanoparticles, with dimensions of several tens of nanometers, were characterized using TEM, SEM-EDX, IR, and XRD. Their electrochemical behavior was investigated in comparison with the CoHCF powder bulk compound. The CoHCF nanoparticles exhibit an electrochemically driven conversion to the bulk one that has been investigated by a chemometric approach in order to establish the best synthetic parameters. The rate and the degree of con…

Materials scienceAqueous solutionCHEMOMETRICMixing (process engineering)Analytical chemistryNanoparticleElectrochemistryelectrochemical behaviorCOBALT HEXACYANOFERRATESurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCobalt hexacyanoferrateCharacterization (materials science)ELECTROCHEMISTRYGeneral EnergyChemical engineeringnanocompoundNanometrePhysical and Theoretical ChemistrySettore CHIM/02 - Chimica FisicaNANO PARTICLES
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A multivariate approach to the study of orichalcum ingots from the underwater Gela's archaeological site

2017

Abstract In this work a careful ICP-OES and ICP-MS investigation of 38 ancient ingots has been performed to determine both major components and trace elements content to find a correlation between the observed different features and the composition. The ingots, recovered in an underwater archaeological site of various finds near Gela (CL, Italy), were previously investigated by X-Ray Fluorescence (XRF) spectroscopy to know the composition of the alloy and it was found that the major elements were copper and zinc, in a ratio compatible with the famous orichalcum similar to the contemporary brass that was considered a precious metal in ancient times. The discovery of huge amount this alloy is…

Multivariate statisticsChemometric approach010401 analytical chemistryMetallurgyMineralogy02 engineering and technologyOrichalcum ingot021001 nanoscience & nanotechnologyLinear discriminant analysis01 natural sciencesArchaeology0104 chemical sciencesAnalytical ChemistryBrassvisual_artPrincipal component analysisOutliervisual_art.visual_art_mediumICP-OESICP-MSUnderwaterIngot0210 nano-technologyGeologySpectroscopy
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First discovery of orichalcum ingots from the remains of a 6th century BC shipwreck near Gela (Sicily) seabed

2017

Ingots recently recovered from the seabed near Gela, a major harbour of Sicily, reveal an unexpected side of ancient metallurgy. The ingots were found near remains of a ship and earthenware dated around the end of the VI century BC and probably coming from the eastern Mediterranean and the Aegean sea. The ingots were analysed by means of X-Ray Fluorescence spectroscopy via a portable spectrometer. Results indicate that they are mostly consist of copper and zinc although many of them have a significant amount of lead. This alloy is nowday called brass, but in ancient time it was know as orichalcum, one of the rarest and most precious alloy along with gold and silver. Only small items of oric…

010506 paleontologyArcheology060102 archaeologyArcheology (arts and humanities)06 humanities and the artsOrichalcum01 natural sciencesSettore CHIM/12 - Chimica Dell'Ambiente E Dei Beni CulturaliX-rays fluorescenceingotsingotOrichalcum ingots X-rays fluorescence archaeometallurgyarchaeometallurgy0601 history and archaeology0105 earth and related environmental sciencesSettore CHIM/02 - Chimica Fisica
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