0000000000939865
AUTHOR
Henk Bolink
Remote modification of bidentate phosphane ligands controlling the photonic properties in their complexes: Enhanced performance of [Cu(RN-xantphos)(N^N)][PF6] in light-emitting electrochemical cells
A series of copper(I) complexes of the type [Cu(HN-xantphos)(N^N)][PF6] and [Cu(BnN-xantphos)(N^N)][PF6], in which N^N = bpy, Mebpy, and Me2bpy, HN-xantphos = 4,6-bis(diphenylphosphanyl)-10H-phenoxazine and BnNxantphos = 10-benzyl-4,6-bis(diphenylphosphanyl)-10H-phenoxazine is described. The single crystal structures of [Cu(HN-xantphos)(Mebpy)][PF6] and [Cu(BnN-xantphos)(Me2bpy)][PF6] confirm the presence of N^N and P^P chelating ligands with the copper(I) atoms in distorted coordination environments. Solution electrochemical and photophysical properties of the BnNxantphos- containing compounds (for which the highest-occupied molecular orbital is located on the phenoxazine moiety) are repor…
Preparation and Characterization of Mixed Halide MAPbI3−xClx Perovskite Thin Films by Three‐Source Vacuum Deposition
Chloride has been extensively used in the preparation of metal halide perovskites such as methylammonium lead iodide (MAPbI3-xClx), but its persistence and role in solution-processed materials has not yet been rationalized. Multiple-source vacuum deposition of perovskites enables a fine control over the thin-film stoichiometry, and allows to incorporate chemical species irrespectively of their solubility. In this communication, we present the first example of mixed MAPbI3-xClx thin films prepared by three-source vacuum deposition using MAI, PbI2 and PbCl2 as precursors. The optoelectronic properties of the material are evaluated through photovoltaic and electro-/photo-luminescent characteri…
CCDC 1445197: Experimental Crystal Structure Determination
Related Article: Sadig Aghazada, Aron J. Huckaba, Antonio Pertegas, Azin Babaei, Giulia Grancini, Iwan Zimmermann, Henk Bolink and Mohammad Khaja Nazeeruddin|2016|Eur.J.Inorg.Chem.||5089|doi:10.1002/ejic.201600971
CCDC 1584756: Experimental Crystal Structure Determination
Related Article: Sarah Keller, Alessandro Prescimone, Henk Bolink, Michele Sessolo, Giulia Longo, Laura Martínez-Sarti, José M. Junquera-Hernández, Edwin C. Constable, Enrique Ortí, Catherine E. Housecroft|2018|Dalton Trans.|47|14263|doi:10.1039/C8DT01338A
CCDC 1584755: Experimental Crystal Structure Determination
Related Article: Sarah Keller, Alessandro Prescimone, Henk Bolink, Michele Sessolo, Giulia Longo, Laura Martínez-Sarti, José M. Junquera-Hernández, Edwin C. Constable, Enrique Ortí, Catherine E. Housecroft|2018|Dalton Trans.|47|14263|doi:10.1039/C8DT01338A
CCDC 1535142: Experimental Crystal Structure Determination
Related Article: Sarah Keller, Alessandro Prescimone, Henk Bolink, Michele Sessolo, Giulia Longo, Laura Martínez-Sarti, José M. Junquera-Hernández, Edwin C. Constable, Enrique Ortí, Catherine E. Housecroft|2018|Dalton Trans.|47|14263|doi:10.1039/C8DT01338A
CCDC 1445196: Experimental Crystal Structure Determination
Related Article: Sadig Aghazada, Aron J. Huckaba, Antonio Pertegas, Azin Babaei, Giulia Grancini, Iwan Zimmermann, Henk Bolink and Mohammad Khaja Nazeeruddin|2016|Eur.J.Inorg.Chem.||5089|doi:10.1002/ejic.201600971
CCDC 1583875: Experimental Crystal Structure Determination
Related Article: Sarah Keller, Alessandro Prescimone, Henk Bolink, Michele Sessolo, Giulia Longo, Laura Martínez-Sarti, José M. Junquera-Hernández, Edwin C. Constable, Enrique Ortí, Catherine E. Housecroft|2018|Dalton Trans.|47|14263|doi:10.1039/C8DT01338A
CCDC 1519073: Experimental Crystal Structure Determination
Related Article: Marta Martínez-Alonso, Jesús Cerdá, Cristina Momblona, Antonio Pertegás, José M. Junquera-Hernández, Aránzazu Heras, Ana M. Rodríguez, Gustavo Espino, Henk Bolink, and Enrique Ortí|2017|Inorg.Chem.|56|10298|doi:10.1021/acs.inorgchem.7b01167
CCDC 1584757: Experimental Crystal Structure Determination
Related Article: Sarah Keller, Alessandro Prescimone, Henk Bolink, Michele Sessolo, Giulia Longo, Laura Martínez-Sarti, José M. Junquera-Hernández, Edwin C. Constable, Enrique Ortí, Catherine E. Housecroft|2018|Dalton Trans.|47|14263|doi:10.1039/C8DT01338A
CCDC 1519074: Experimental Crystal Structure Determination
Related Article: Marta Martínez-Alonso, Jesús Cerdá, Cristina Momblona, Antonio Pertegás, José M. Junquera-Hernández, Aránzazu Heras, Ana M. Rodríguez, Gustavo Espino, Henk Bolink, and Enrique Ortí|2017|Inorg.Chem.|56|10298|doi:10.1021/acs.inorgchem.7b01167
CCDC 1535141: Experimental Crystal Structure Determination
Related Article: Sarah Keller, Alessandro Prescimone, Henk Bolink, Michele Sessolo, Giulia Longo, Laura Martínez-Sarti, José M. Junquera-Hernández, Edwin C. Constable, Enrique Ortí, Catherine E. Housecroft|2018|Dalton Trans.|47|14263|doi:10.1039/C8DT01338A
CCDC 1584754: Experimental Crystal Structure Determination
Related Article: Sarah Keller, Alessandro Prescimone, Henk Bolink, Michele Sessolo, Giulia Longo, Laura Martínez-Sarti, José M. Junquera-Hernández, Edwin C. Constable, Enrique Ortí, Catherine E. Housecroft|2018|Dalton Trans.|47|14263|doi:10.1039/C8DT01338A
Data Underpinning - Tuning the emission of cationic iridium (III) complexes towards the red through methoxy substitution of the cyclometalating ligand
EZ-C acknowledges CFI (Canadian Foundation for Innovation), NSERC (the Natural Sciences and Engineering Research Council of Canada), FQRNT (Le Fonds québécois de la recherche sur la nature et les technologies) and the University of St Andrews for financial support. C. R-C. would like to thank the MINECO for the financial support of this research in the framework of project CTQ2010-17481, the Junta de Andalucía (CICyE) for special financial support (P08-FQM-4011 and P10-FQM-6703) and the MECD (Spanish Ministry of Education, Culture, and Sport) for an FPU grant. This work has been supported by the Spanish Ministry of Economy and Competitiveness (MINECO) (MAT2014-55200), the Generalitat Valenc…
CCDC 1535144: Experimental Crystal Structure Determination
Related Article: Sarah Keller, Alessandro Prescimone, Henk Bolink, Michele Sessolo, Giulia Longo, Laura Martínez-Sarti, José M. Junquera-Hernández, Edwin C. Constable, Enrique Ortí, Catherine E. Housecroft|2018|Dalton Trans.|47|14263|doi:10.1039/C8DT01338A
CCDC 1584752: Experimental Crystal Structure Determination
Related Article: Sarah Keller, Alessandro Prescimone, Henk Bolink, Michele Sessolo, Giulia Longo, Laura Martínez-Sarti, José M. Junquera-Hernández, Edwin C. Constable, Enrique Ortí, Catherine E. Housecroft|2018|Dalton Trans.|47|14263|doi:10.1039/C8DT01338A
CCDC 1584753: Experimental Crystal Structure Determination
Related Article: Sarah Keller, Alessandro Prescimone, Henk Bolink, Michele Sessolo, Giulia Longo, Laura Martínez-Sarti, José M. Junquera-Hernández, Edwin C. Constable, Enrique Ortí, Catherine E. Housecroft|2018|Dalton Trans.|47|14263|doi:10.1039/C8DT01338A
CCDC 1535143: Experimental Crystal Structure Determination
Related Article: Sarah Keller, Alessandro Prescimone, Henk Bolink, Michele Sessolo, Giulia Longo, Laura Martínez-Sarti, José M. Junquera-Hernández, Edwin C. Constable, Enrique Ortí, Catherine E. Housecroft|2018|Dalton Trans.|47|14263|doi:10.1039/C8DT01338A