0000000000940537
AUTHOR
Munirathnam Manda
Dimeric Mn(ii), Co(ii), Ni(ii) and Cu(ii) complexes of a common carboxylate-appended (2-pyridyl)alkylamine ligand: structure, magnetism and DFT study
Four new complexes of composition [MII2(L3)2(CH3OH)2](ClO4)2 (M = Mn, 1; Co, 2; Ni, 3) and [CuII2(L3)2](ClO4)2 (4) (L3(−) = 3-[2-(((6-methyl)pyridin-2-yl)methyl){(dimethylamino)ethyl}-amino]propionate) have been synthesized and characterized. Structural analysis reveals that 1–4 are discrete syn–anti carboxylate-bridged binuclear coordination complexes with a {MII2(–O–C–O–)2}2+ structural motif. In 1–3 distorted octahedral MN3O3 and in 4 distorted square pyramidal CuN3O2 coordination is satisfied at each M(II) center by three N (a pyridyl and two tertiary aliphatic amines) and a carboxylate O of the ligand, and an O of the carboxylate group. In 1–3 the M(II) center is also coordinated by a …
CCDC 1965761: Experimental Crystal Structure Determination
Related Article: Munirathnam Manda, Himanshu Arora, Arunava Sengupta, Shashi Kant, Francesc Lloret, Rabindranath Mukherjee|2021|New J.Chem.|45|16019|doi:10.1039/D1NJ01150B
CCDC 1965763: Experimental Crystal Structure Determination
Related Article: Munirathnam Manda, Himanshu Arora, Arunava Sengupta, Shashi Kant, Francesc Lloret, Rabindranath Mukherjee|2021|New J.Chem.|45|16019|doi:10.1039/D1NJ01150B
CCDC 1965760: Experimental Crystal Structure Determination
Related Article: Munirathnam Manda, Himanshu Arora, Arunava Sengupta, Shashi Kant, Francesc Lloret, Rabindranath Mukherjee|2021|New J.Chem.|45|16019|doi:10.1039/D1NJ01150B
CCDC 1965762: Experimental Crystal Structure Determination
Related Article: Munirathnam Manda, Himanshu Arora, Arunava Sengupta, Shashi Kant, Francesc Lloret, Rabindranath Mukherjee|2021|New J.Chem.|45|16019|doi:10.1039/D1NJ01150B