0000000000954590
AUTHOR
Arpita Jana
A Series of MIICuII3 Stars (M = Mn, Ni, Cu, Zn) Exhibiting Unusual Magnetic Properties
The work in this report describes the syntheses, electrospray ionization mass spectromtery, structures, and experimental and density functional theoretical (DFT) magnetic properties of four tetrametallic stars of composition [M(II)(Cu(II)L)3](ClO4)2 (1, M = Mn; 2, M = Ni; 3, M = Cu; 4, M = Zn) derived from a single-compartment Schiff base ligand, N,N'-bis(salicylidene)-1,4-butanediamine (H2L), which is the [2 + 1] condensation product of salicylaldehyde and 1,4-diaminobutane. The central metal ion (Mn(II), Ni(II), Cu(II), or Zn(II)) is linked with two μ2-phenoxo bridges of each of the three [Cu(II)L] moieties, and thus the central metal ion is encapsulated in between three [Cu(II)L] units. …
Structures and Magnetic Properties of Bis(μ‐phenoxido), Bis(μ‐phenoxido)‐μ‐carboxylato and Bis(μ‐phenoxido)bis(μ‐carboxylato) Fe III Ni II Compounds – Magnetostructural Correlations
This report describes the syntheses, characterization, crystal structures and magnetic properties of five dinuclear FeIIINiII compounds derived from two Robson-type tetraiminodiphenol macrocyclic ligands H2L1 and H2L2, which are the [2+2] condensation products of 4-ethyl-2,6-diformylphenol and 1,3-diaminopropane (for H2L1) or 2,2-dimethyl-1,3-diaminopropane (for H2L2). The compositions of the compounds are [FeIII(N3)2L1NiII(H2O)2](ClO4) (1), [FeIII(benzoato)L1NiII(H2O)(μ1,3-benzoato)](ClO4) (2), [FeIII(benzoato)L2NiII(H2O)(μ1,3-benzoato)](ClO4) (3), [FeIIIL2NiII(μ1,3-acetato)2](ClO4)·H2O (4) and [FeIIIL2NiII(μ1,3-propionato)2](ClO4)·H2O (5). The bridging moieties between the two metal ions …
Syntheses, structures, and magnetic properties of diphenoxo-bridged Cu(II)Ln(III) and Ni(II)(low-spin)Ln(III) compounds derived from a compartmental ligand (Ln = Ce-Yb).
Syntheses, characterization, and magnetic properties of a series of diphenoxo-bridged discrete dinuclear M(II)Ln(III) complexes (M = Cu or Ni, Ln = Ce-Yb) derived from the compartmental Schiff base ligand, H(2)L, obtained on condensation of 3-ethoxysalicylaldehyde with trans-1,2-diaminocyclohexane, are described. Single crystal X-ray structures of eight Cu(II)Ln(III) compounds (Ln = Ce (1), Pr (2), Nd (3), Sm (4), Tb (7), Ho (9), Er (10), and Yb (12)) and three Ni(II)Ln(III) (Ln = Ce (13), Sm (16), and Gd (18)) compounds have been determined. Considering the previously reported structure of the Cu(II)Gd(III) (6) compound (Eur. J. Inorg. Chem. 2005, 1500), a total of twelve structures are di…
CCDC 999771: Experimental Crystal Structure Determination
Related Article: Sujit Sasmal, Shuvayan Roy, Luca Carrella, Arpita Jana, Eva Rentschler, Sasankasekhar Mohanta|2015|Eur.J.Inorg.Chem.||680|doi:10.1002/ejic.201402866
CCDC 999768: Experimental Crystal Structure Determination
Related Article: Sujit Sasmal, Shuvayan Roy, Luca Carrella, Arpita Jana, Eva Rentschler, Sasankasekhar Mohanta|2015|Eur.J.Inorg.Chem.||680|doi:10.1002/ejic.201402866
CCDC 1048420: Experimental Crystal Structure Determination
Related Article: Suraj Mondal, Shuvankar Mandal, Luca Carrella, Arpita Jana, Michel Fleck, Andreas Köhn, Eva Rentschler, and Sasankasekhar Mohanta|2015|Inorg.Chem.|54|117|doi:10.1021/ic501900d
CCDC 1048423: Experimental Crystal Structure Determination
Related Article: Suraj Mondal, Shuvankar Mandal, Luca Carrella, Arpita Jana, Michel Fleck, Andreas Köhn, Eva Rentschler, and Sasankasekhar Mohanta|2015|Inorg.Chem.|54|117|doi:10.1021/ic501900d
CCDC 999772: Experimental Crystal Structure Determination
Related Article: Sujit Sasmal, Shuvayan Roy, Luca Carrella, Arpita Jana, Eva Rentschler, Sasankasekhar Mohanta|2015|Eur.J.Inorg.Chem.||680|doi:10.1002/ejic.201402866
CCDC 1048421: Experimental Crystal Structure Determination
Related Article: Suraj Mondal, Shuvankar Mandal, Luca Carrella, Arpita Jana, Michel Fleck, Andreas Köhn, Eva Rentschler, and Sasankasekhar Mohanta|2015|Inorg.Chem.|54|117|doi:10.1021/ic501900d
CCDC 1048422: Experimental Crystal Structure Determination
Related Article: Suraj Mondal, Shuvankar Mandal, Luca Carrella, Arpita Jana, Michel Fleck, Andreas Köhn, Eva Rentschler, and Sasankasekhar Mohanta|2015|Inorg.Chem.|54|117|doi:10.1021/ic501900d
CCDC 999770: Experimental Crystal Structure Determination
Related Article: Sujit Sasmal, Shuvayan Roy, Luca Carrella, Arpita Jana, Eva Rentschler, Sasankasekhar Mohanta|2015|Eur.J.Inorg.Chem.||680|doi:10.1002/ejic.201402866
CCDC 999769: Experimental Crystal Structure Determination
Related Article: Sujit Sasmal, Shuvayan Roy, Luca Carrella, Arpita Jana, Eva Rentschler, Sasankasekhar Mohanta|2015|Eur.J.Inorg.Chem.||680|doi:10.1002/ejic.201402866