Author: G. H. Hu

0000000000955795

AUTHOR

G. H. Hu

showing 1 related works from this author

Chemical Modification of Nitrile to Oxazoline Functionality on a Styrene-Acrylonitrile Copolymer in the Melt

1998

Oxazoline is a very interesting functionality for reactive extrusion and other applications. In this paper, we report the possibility of chemically transforming nitrile group attached to a copolymer of styrene and acrylonitrile (SAN) to oxazoline group using 2-amino-ethanol (AE). The chemical modification of SAN with AE was done in the molten state. Among various catalysts tested, zinc acetate turned out to be the most efficient. The effects of the catalyst concentration, temperature and mixing on the overall kinetics were studied. The formation of the expected oxazoline functionality was confirmed by infrared spectroscopy and by reacting with 1-naphthylacetic acid. The reaction between the…

Materials sciencecompatibilizationPolymers and PlasticsNitrilenitrilepoly-(butylene terephthalate)Chemical modificationGeneral ChemistryReactive extrusionCompatibilizationOxazolineStyrenechemistry.chemical_compoundSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialiSANchemistryPolymer chemistryMaterials ChemistryCeramics and CompositesCopolymerOrganic chemistryPolyamide 6AcrylonitrileoxazolineJournal of Macromolecular Science, Part A

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