The Synthesis of Quinoline‐based Tin Complexes with Pendant Schiff Bases

2019

Whilst pursuing the synthetic utility of quinoline‐based tin complexes, Me2Sn(Quin‐NO2)2 (1) and Ph2Sn(Quin‐NO2)2 (2) (Quin‐NO2 = 5‐nitroquinolino‐8‐oate) were synthesized bearing coordinatively inert nitro groups. Conventional reduction methodologies successfully converted 1 to Me2Sn(Quin‐NH2)2 (3) and 2 to Ph2Sn(Quin‐NH2)2 (4) (Quin‐NH2 = 5‐aminoquinolino‐8‐oate). The synthetically useful amine groups proved difficult to exploit in the presence of the central tin atom, however, a complete Schiff base functionalized Sn complex of the dimethyltin pro‐ligand Me2Sn(Quin‐py)2 (6) was successfully synthesized from 5‐[(pyridin‐2‐ylmethylene)amino]quinolin‐8‐ol (HQuin‐py; 5) in good yield via an …

The Synthesis of Quinoline-based Tin Complexes with Pendant Schiff Bases

2019