0000000000968676
AUTHOR
I. A. Gural'skiy
Pyridinium bis(pyridine-jN)tetrakis(thiocyanato-cyanato-jN)ferrate(III)
In the title compound, (C5H6N)[Fe(NCS)4(C5H5N)2], the FeIII ion is coordinated by four thiocyanate N atoms and two pyridine N atoms in a trans arrangement, forming an FeN6 polyhedron with a slightly distorted octahedral geometry. Charge balance is achieved by one pyridinium cation bound to the complex anion via N—HS hydrogen bonding. The asymmetric unit consists of one FeIII cation, four thiocyanate anions, two coordinated pyridine molecules and one pyridinium cation. The structure exhibits – interactions between pyridine rings [centroid–centroid distances = 3.7267 (2), 3.7811 (2) and 3.8924 (2) A˚ ]. The N atom and a neighboring C atom of the pyridinium cation are statistically disordered …
CCDC 939036: Experimental Crystal Structure Determination
Related Article: S. I. Shylin, I. A. Gural'skiy, M. Haukka, A. A. Kapshuk andE. V. Prisyazhnaya|2013|Acta Crystallogr.,Sect.E:Struct.Rep.Online|69|m298|doi:10.1107/S1600536813011628
CCDC 954205: Experimental Crystal Structure Determination
Related Article: S. I. Shylin, I. A. Gural'skiy, M. Haukka, I. A. Golenya|2013|Acta Crystallogr.,Sect.E:Struct.Rep.Online|69|m280|doi:10.1107/S1600536813010362