0000000000971038
AUTHOR
L. Rublova
Synthesis, crystal and molecular-electronic structure, and kinetic investigation of two new sterically hindered isomeric forms of the dimethyl[methyl(phenylsulfonyl)amino]benzenesulfonyl chloride
Two new structural isomers – 2,4-dimethyl-5-[methyl(phenylsulfonyl)amino]benzenesulfonyl chloride (1) and 2,4-dimethyl-3-[methyl(phenylsulfonyl)amino]benzenesulfonyl chloride (2) were synthesized by interaction of N-(2,4-dimethylphenyl)-N-methyl-benzenesulfonamide or N-(2,6-dimethylphenyl)-N-methylbenzenesulfonamide with chlorosulfonic acid. Both compounds have been structurally characterized by X-ray single crystal diffraction at 100 K. The crystals of 1 are triclinic: space group View the MathML source, a = 8.1542(2), b = 11.0728(3), c = 11.2680(3) Å, α = 116.557(3), β = 95.155(2), γ = 108.258(2)°, V = 831.97(4) Å3, Z = 2, R = 0.0251 for 2429 reflections; the crystals of 2 are monoclinic:…
CCDC 948230: Experimental Crystal Structure Determination
Related Article: L. Rublova, B. Zarychta, V. Olijnyk, B. Mykhalichko|2017|J.Mol.Struct.|1137|1|doi:10.1016/j.molstruc.2017.02.016
CCDC 948229: Experimental Crystal Structure Determination
Related Article: L. Rublova, B. Zarychta, V. Olijnyk, B. Mykhalichko|2017|J.Mol.Struct.|1137|1|doi:10.1016/j.molstruc.2017.02.016