0000000000985005
AUTHOR
Jashobanta Sahoo
Coordinatively Unsaturated Lanthanide(III) Helicates: Luminescence Sensors for Adenosine Monophosphate in Aqueous Media
Coordinatively unsaturated double-stranded helicates [(H2 L)2 Eu2 (NO3 )2 (H2 O)4 ](NO3 )4 , [(H2 L)2 Tb2 (H2 O)6 ](NO3 )6 , and [(H2 L)2 Tb2 (H2 O)6 ]Cl6 (H2 L=butanedioicacid-1,4-bis[2-(2-pyridinylmethylene)hydrazide]) are easily obtained by self-assembly from the ligand and the corresponding lanthanide(III) salts. The complexes are characterized by X-ray crystallography showing the helical arrangement of the ligands. Co-ligands at the metal ions can be easily substituted by appropriate anions. A specific luminescence response of AMP in presence of ADP, ATP, and other anions is observed. Specificity is assigned to the perfect size match of AMP to bridge the two metal centers and to replac…
CCDC 1453996: Experimental Crystal Structure Determination
Related Article: Jashobanta Sahoo, Rajendran Arunachalam, Palani S. Subramanian, Eringathodi Suresh, Arto Valkonen, Kari Rissanen, Markus Albrecht|2016|Angew.Chem.,Int.Ed.|55|9625|doi:10.1002/anie.201604093
CCDC 1453997: Experimental Crystal Structure Determination
Related Article: Jashobanta Sahoo, Rajendran Arunachalam, Palani S. Subramanian, Eringathodi Suresh, Arto Valkonen, Kari Rissanen, Markus Albrecht|2016|Angew.Chem.,Int.Ed.|55|9625|doi:10.1002/anie.201604093
CCDC 1458068: Experimental Crystal Structure Determination
Related Article: Jashobanta Sahoo, Rajendran Arunachalam, Palani S. Subramanian, Eringathodi Suresh, Arto Valkonen, Kari Rissanen, Markus Albrecht|2016|Angew.Chem.,Int.Ed.|55|9625|doi:10.1002/anie.201604093