0000000000991645
AUTHOR
Vincenzo Sorrentino
DC Grids for Supporting AC Power System during Failure Events: Experimental Testing of a Urban Case Study
AC power systems and their devices can be subjected to different failure events due to thermal, environmental, and aging phenomena. In this context, DC grids intervention could mitigate customers black-out by adequately controlling their internal resources (renewable generators and storage systems). In this paper, failure events concerning HV/MV transformer are considered. Possible actions to support the AC grid to avoid interruption in load areas are analyzed and experimentally validated. Tests campaigns are carried out taking advantage of a research nanogrid infrastructure available at ENEA Centre of Portici. It consists of indoor equipment able to emulate actual generation, load and stor…
A Click Chemistry-Based “Grafting Through” Approach to the Synthesis of a Biorelevant Polymer Brush
A new biorelevant polymer brush showing a polybenzofulvene backbone was synthesized by a ‘‘grafting through’’ approach based on click chemistry and spontaneous polymerization reactions. The easy polymerization of the relatively complex monomer (6-MOEG-9-TM-BF3k) suggests the existence of a particularly efficient recognition process capable of pre-organizing the monomer molecules for the spontaneous polymerization. 13C-NMR spectroscopy as well as UV-vis and fluorescence spectroscopy suggested for poly-6-MOEG-9-TM-BF3k the features of a vinyl (1,2) p-stacked polymer. The new polybenzofulvene derivative was found to interact with water at room temperature to give clear water solutions, but TEM…