0000000001004114

AUTHOR

Jordi Benet-buchholz

showing 4 related works from this author

Intramolecular proton transfer boosts water oxidation catalyzed by a Ru complex

2015

We introduce a new family of complexes with the general formula [Run(tda)(py)2]m+ (n = 2, m = 0, 1; n = 3, m = 1, 2+; n = 4, m = 2, 32+), with tda2– being [2,2′:6′,2″-terpyridine]-6,6″-dicarboxylate, including complex [RuIV(OH)(tda-κ-N3O)(py)2]+, 4H+, which we find to be an impressive water oxidation catalyst, formed by hydroxo coordination to 32+ under basic conditions. The complexes are synthesized, isolated, and thoroughly characterized by analytical, spectroscopic (UV–vis, nuclear magnetic resonance, electron paramagnetic resonance), computational, and electrochemical techniques (cyclic voltammetry, differential pulse voltammetry, coulometry), …

Coordination numberInorganic chemistryGeneral ChemistryElectrochemistryBiochemistryCatalysislaw.inventionCrystallographychemistry.chemical_compoundColloid and Surface ChemistryCatalytic oxidationchemistryOxidation statelawDifferential pulse voltammetryCarboxylateCyclic voltammetryElectron paramagnetic resonance
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CCDC 1421699: Experimental Crystal Structure Determination

2015

Related Article: Roc Matheu, Mehmed Z. Ertem, Jordi Benet-Buchholz, Eugenio Coronado, Victor S. Batista, Xavier Sala, and Antoni Llobet|2015|J.Am.Chem.Soc.|137|10786|doi:10.1021/jacs.5b06541

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(Pyridine)-(22':6'2''-terpyridine-66''-dicarboxylato)-ruthenium bis(hexafluorophosphate)Experimental 3D Coordinates
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CCDC 1421700: Experimental Crystal Structure Determination

2015

Related Article: Roc Matheu, Mehmed Z. Ertem, Jordi Benet-Buchholz, Eugenio Coronado, Victor S. Batista, Xavier Sala, and Antoni Llobet|2015|J.Am.Chem.Soc.|137|10786|doi:10.1021/jacs.5b06541

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatesbis(Pyridine-N)-(22':6'2''-terpyridine-66''-dicarboxylato-NN'N''OO')-ruthenium bis(pyridine-N)-(22':6'2''-terpyridine-66''-dicarboxylato-NN'N''O)-ruthenium methanol solvate monohydrate
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CCDC 1421701: Experimental Crystal Structure Determination

2015

Related Article: Roc Matheu, Mehmed Z. Ertem, Jordi Benet-Buchholz, Eugenio Coronado, Victor S. Batista, Xavier Sala, and Antoni Llobet|2015|J.Am.Chem.Soc.|137|10786|doi:10.1021/jacs.5b06541

bis(Pyridine)-(22':6'2''-terpyridine-66''-dicarboxylato)-ruthenium hexafluorophosphateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct