0000000001004174

AUTHOR

Vladimir I. Feldman

showing 3 related works from this author

Efficient size control of copper nanoparticles generated in irradiated aqueous solutions of star-shaped polyelectrolyte containers

2015

Physical chemistry, chemical physics 17(17), 11490-11498(2015). doi:10.1039/C5CP00269A

PolymersSurface PropertiesInorganic chemistryNucleationGeneral Physics and AstronomyNanoparticlechemistry.chemical_elementMetal Nanoparticleslaw.inventionchemistry.chemical_compoundElectrolyteslawPhysical and Theoretical ChemistryParticle SizeElectron paramagnetic resonanceAcrylic acidAqueous solutionChemistryWater540CopperPolyelectrolyteSolutionsCrystallographyTransmission electron microscopyddc:540Copper
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Photochemistry of the H2O/CO System Revisited : The HXeOH···CO Complex in a Xenon Matrix

2017

We report on the complex of a noble-gas hydride HXeOH with carbon monoxide. This species is prepared via the annealing-induced H + Xe + OH···CO reaction in a xenon matrix, the OH···CO complexes being produced by VUV photolysis of the H2O···CO complexes. The H–Xe stretching mode of the HXeOH···CO complex absorbs at 1590.3 cm–1 and it is blue-shifted by 12.7 cm–1 from the H–Xe stretching band of HXeOH monomer. The observed blue shift indicates the stabilization of the H–Xe bond upon complexation, which is characteristic of complexes of noble-gas hydrides. The HXeOH···CO species is the first complex of a noble-gas hydride with carbon monoxide and the second observed complex of HXeOH. On the ba…

chemistry.chemical_element02 engineering and technology010402 general chemistryPhotochemistry01 natural sciencescarbon monoxidechemistry.chemical_compoundXenonmatricesNon-covalent interactionsMoleculegasesPhysical and Theoretical Chemistryta116chemistry.chemical_classificationphotochemistryHydrideIntermolecular forcePhotodissociation021001 nanoscience & nanotechnology0104 chemical sciencesMonomerchemistryH2O/CO system0210 nano-technologyCarbon monoxideJournal of Physical Chemistry C
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Photochemistry of the H2O/CO System Revisited : The HXeOH···CO Complex in a Xenon Matrix

2018

We report on the complex of a noble-gas hydride HXeOH with carbon monoxide. This species is prepared via the annealing-induced H + Xe + OH···CO reaction in a xenon matrix, the OH···CO complexes being produced by VUV photolysis of the H2O···CO complexes. The H–Xe stretching mode of the HXeOH···CO complex absorbs at 1590.3 cm–1 and it is blue-shifted by 12.7 cm–1 from the H–Xe stretching band of HXeOH monomer. The observed blue shift indicates the stabilization of the H–Xe bond upon complexation, which is characteristic of complexes of noble-gas hydrides. The HXeOH···CO species is the first complex of a noble-gas hydride with carbon monoxide and the second observed complex of HXeOH. On the ba…

kaasutH2O/CO systemvalokemiamatriisithiilimonoksidi
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