0000000001005455

AUTHOR

Adrien T. Normand

showing 80 related works from this author

Insertion Reactions of Neutral Phosphidozirconocene Complexes as a Convenient Entry into Frustrated Lewis Pair Territory

2016

International audience; Neutral phosphidozirconocene complexes [Cp2Zr(PR2)Me] (Cp=cyclopentadienyl; 1a: R=cyclohexyl (Cy); 1b: R=mesityl (Mes); 1c: R=tBu) undergo insertion into the Zr-P bond by non-enolisable carbonyl building blocks (O=CRR), such as benzophenone, aldehydes, paraformaldehyde or CO2, to give [Cp2Zr(OCRRPR2)Me] (3-7). Depending on the steric bulk around P, complexes 3-7 react with B(C6F5)(3) to give O-bridged cationic zirconocene dimers that display typical frustrated Lewis pair (FLP)/ambiphilic ligand behaviour. Thus, the reaction of {[Cp2Zr(-OCHPhPCy2)][MeB(C6F5)(3)]}(2) (10a) with chalcone results in 1,4 addition of the Zr+/P FLP, whereas the reaction of {[Cp2Zr(-OCHFcPCy…

Steric effectsChalconeStereochemistryzirconiumc-h activation010402 general chemistry01 natural sciencesMedicinal chemistry[ CHIM ] Chemical SciencesCatalysisFrustrated Lewis pairinsertionchemistry.chemical_compoundCyclopentadienyl complexx-ray structuresphosphinidene complexesBenzophenone[CHIM]Chemical SciencesParaformaldehydezr-p bondzirconocene-phosphido complexesmolecular-structure010405 organic chemistryLigandphosphidesOrganic ChemistryCationic polymerizationcrystal-structureGeneral Chemistry0104 chemical sciencesfunctionalized ligandsbis(trimethylsilyl)phosphido complexeschemistryfrustrated Lewis pairsphosphinoaryloxide complexesambiphilic ligands
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Phosphido- and Amidozirconocene Cation-Based Frustrated Lewis Pair Chemistry

2015

Methyl abstraction from neutral [Cp2ZrMe(ERR')] complexes 1 (E = N, P; R, R' = alkyl, aryl) with either B(C6F5)3 or [Ph3C][B(C6F5)4] results in the formation of [Cp2Zr(ERR')][X] complexes 2 (X(-) = MeB(C6F5)3(-), B(C6F5)4(-)). The X-ray structure of amido complexes [Cp2Zr(NPh2)][MeB(C6F5)3] (2d) and [Cp2Zr(N(t)BuAr)][B(C6F5)4] (2e', Ar = 3,5-C6H3(CH3)2) is reported, showing a sterically dependent Zr/N-π interaction. Complexes 2 catalyze the hydrogenation of electron-rich olefins and alkynes under mild conditions (room temperature, 1.5 bar H2). Complex 2e binds CO2, giving [Cp2Zr(CO2)(N(t)BuAr)]2[MeB(C6F5)3]2 (3e). Amido complex 2d reacts with benzaldehyde yielding [Cp2Zr(OCH2Ph)((OC)PhNPh2)…

chemistry.chemical_classificationSteric effectsStereochemistryArylGeneral ChemistryBiochemistryMedicinal chemistryCatalysisFrustrated Lewis pairBenzaldehydechemistry.chemical_compoundColloid and Surface ChemistrychemistryDiphenylacetyleneAlkylJournal of the American Chemical Society
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Titanium imido complexes stabilised by bis(iminophosphoranyl)methanide ligands: the influence of N-substituents on solution dynamics and reactivity

2014

Terminal titanium imido complexes of the general formula [Ti(N(t)Bu)Cl{CH(Ph2PNR)2}] 4 (R = Ph, (i)Pr, (t)Bu) are reported. These compounds were synthesized from the corresponding Li adducts 3 of BIPMH (bis(iminophosphoranyl)methanide) and Mountford's complex [Ti(N(t)Bu)Cl2(Py)3]. The crystal structures of two of the Ti complexes (R = Ph, (t)Bu) and two of the Li compounds (R = (i)Pr, (t)Bu) are reported. Dynamic solution NMR spectroscopy reveals a dynamic isomerisation process in the case of the Ti complex 4c (R = (t)Bu). DFT studies showed that this dynamic process comes from steric repulsion between the imido ligand and the (t)Bu N-substituents on the BIPMH ligand. Complexes 4 were teste…

chemistry.chemical_classificationLigandAlkyneNuclear magnetic resonance spectroscopyCrystal structurePhotochemistryMedicinal chemistryAdductInorganic Chemistrychemistry.chemical_compoundchemistryPhenylacetyleneReactivity (chemistry)Hydroamination[CHIM.OTHE]Chemical Sciences/OtherComputingMilieux_MISCELLANEOUS
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Phosphasalen group IV metal complexes: synthesis, characterization and ring opening polymerization of lactide.

2020

International audience; We report the synthesis of a series of Zr and Ti complexes bearing phosphasalen which differs from salen by the incorporation of two P atoms in the ligand backbone. The reaction of phosphasalen proligands (1a-1c)H2 with Zr(CH2Ph)4 led to different products depending on the nature of the N,N-linker in the ligand. In case of ethylene-linked phosphasalen, octahedral Zr complex 2a formed as a single stereoisomer in trans geometry. With the phenylene linker, it was shown by dynamic NMR spectroscopy that complex 2b exists as a mixture of trans and cis-β isomers in solution, both enantiomers (Δ and Λ) of the cis-β isomer being in fast equilibrium with respect to the NMR tim…

010402 general chemistryLIGANDS SYNTHESIS01 natural sciencesRing-opening polymerizationCoordination complexInorganic ChemistryINDIUM COMPLEXESOctahedral molecular geometry[CHIM]Chemical SciencesSALALEN COMPLEXESCYCLIC ESTERSCOORDINATION CHEMISTRYZIRCONIUM COMPLEXES; COORDINATION CHEMISTRY; SALALEN COMPLEXES; LIGANDS SYNTHESIS; INDIUM COMPLEXES; SALEN LIGANDS; CYCLIC ESTERS; INITIATORS; CATALYSIS; ALUMINUMchemistry.chemical_classification010405 organic chemistryLigandCATALYSISCationic polymerizationNuclear magnetic resonance spectroscopyALUMINUM0104 chemical sciencesCrystallographychemistrySALEN LIGANDSAlkoxy groupINITIATORS[CHIM.OTHE]Chemical Sciences/OtherIsomerizationZIRCONIUM COMPLEXESDalton transactions (Cambridge, England : 2003)
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Coordinatively Unsaturated Amidotitanocene Cations with Inverted σ and π Bond Strengths: Controlled Release of Aminyl Radicals and Hydrogenation/Dehy…

2021

Cationic amidotitanocene complexes [Cp2 Ti(NPhAr)][B(C6 F5 )4 ] (Cp=η5 -C5 H5 ; Ar=phenyl (1 a), p-tolyl (1 b), p-anisyl (1 c)) were isolated. The bonding situation was studied by DFT (Density Functional Theory) using EDA-NOCV (Energy Decomposition Analysis with Natural Orbitals for Chemical Valence). The polar Ti-N bond in 1 a-c features an unusual inversion of σ and π bond strengths responsible for the balance between stability and reactivity in these coordinatively unsaturated species. In solution, 1 a-c undergo photolytic Ti-N cleavage to release Ti(III) species and aminyl radicals ⋅NPhAr. Reaction of 1 b with H3 BNHMe2 results in fast homolytic Ti-N cleavage to give [Cp2 Ti(H3 BNHMe2 )…

Olefin fiberValence (chemistry)010405 organic chemistryBond strengthChemistryRadicalOrganic ChemistryGeneral Chemistry010402 general chemistry01 natural sciencesMedicinal chemistryCatalysis0104 chemical sciencesHomolysisCatalysis[CHIM]Chemical SciencesDehydrogenationReactivity (chemistry)ComputingMilieux_MISCELLANEOUSChemistry – A European Journal
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A Route toward (Aminomethyl)cyclopentadienide Ligands and Their Group 4 Metal Complexes

2018

International audience

Zirconium010405 organic chemistryChemistrychemistry.chemical_element010402 general chemistry01 natural sciences3. Good health0104 chemical sciencesInorganic ChemistryMetalGroup (periodic table)visual_artPolymer chemistryvisual_art.visual_art_medium[CHIM.COOR]Chemical Sciences/Coordination chemistryComputingMilieux_MISCELLANEOUSTitanium
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ChemInform Abstract: Phosphido- and Amidozirconocene Cation-Based Frustrated Lewis Pair Chemistry.

2016

Methyl abstraction from neutral [Cp2ZrMe(ERR′)] complexes 1 (E = N, P; R, R′ = alkyl, aryl) with either B(C6F5)3 or [Ph3C][B(C6F5)4] results in the formation of [Cp2Zr(ERR′)][X] complexes 2 (X– = MeB(C6F5)3–, B(C6F5)4–). The X-ray structure of amido complexes [Cp2Zr(NPh2)][MeB(C6F5)3] (2d) and [Cp2Zr(NtBuAr)][B(C6F5)4] (2e′, Ar = 3,5-C6H3(CH3)2) is reported, showing a sterically dependent Zr/N−π interaction. Complexes 2 catalyze the hydrogenation of electron-rich olefins and alkynes under mild conditions (room temperature, 1.5 bar H2). Complex 2e binds CO2, giving [Cp2Zr(CO2)(NtBuAr)]2[MeB(C6F5)3]2 (3e). Amido complex 2d reacts with benzaldehyde yielding [Cp2Zr(OCH2Ph)((OC)PhNPh2)][MeB(C6F5…

chemistry.chemical_classificationBenzaldehydeSteric effectschemistry.chemical_compoundchemistryArylGeneral MedicineDiphenylacetyleneMedicinal chemistryAlkylFrustrated Lewis pairChemInform
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Direct P-functionalization of azobenzene by a cationic phosphidozirconocene complex.

2016

International audience; We report that the cationic phosphidozirconocene complex [(eta(5)-C5H5)(2)Zr(PCy2)][CH3B(C6F5)(3)] (II) reacts with azobenzene, resulting in the expedient formation of Zr complex (2) bound to a tridentate PNN ligand. This reaction proceeds by a mechanism of cooperative nucleophilic substitution of hydrogen. The intermediate sigma(H) adduct (1) has been characterized by NMR spectroscopy.

ortho-acylationHydrogenaromatic azo-compoundschemistry.chemical_element[CHIM.INOR]Chemical Sciences/Inorganic chemistry010402 general chemistryBioinformatics01 natural sciences[ CHIM ] Chemical SciencesAdductalcoholsInorganic Chemistrychemistry.chemical_compoundc-h functionalizationPolymer chemistryNucleophilic substitution[CHIM]Chemical Sciences010405 organic chemistryChemistryLigandCationic polymerizationcinnolinium salts[ CHIM.INOR ] Chemical Sciences/Inorganic chemistryNuclear magnetic resonance spectroscopy0104 chemical sciences3. Good healthAzobenzeneazoxybenzenesalpha-oxocarboxylic acidsazoareneshydrogennucleophilic-substitutionSurface modificationDalton transactions (Cambridge, England : 2003)
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Synthetic Endeavors toward Titanium Based Frustrated Lewis Pairs with Controlled Electronic and Steric Properties

2015

A new family of cationic Ti complexes 4′ with a pendant phosphine of general formula [CpCpPTiOAr][BPh4] (Cp = η5-C5H5; CpP = η5-C5H4(CMe2)PR2) has been prepared in four steps from 6,6-dimethylfulvene. These complexes were designed to behave as Ti based frustrated Lewis pairs (FLPs). The key synthetic step is a reduction–oxidation sequence from [CpCpPTiClOAr] complexes 3 using lithium phosphide salts as the reductants and ferricinium tetraphenylborate as the oxidant. Four complexes have been structurally characterized by X-ray diffraction and show elongated Ti–P bonds, above 2.60 A. One complex (4b′: OAr = 2,6-Me2C6H3; PR2 = PCy2) reacted with benzaldehyde to form a typical FLP activation pr…

Steric effectsTetraphenylboratePhosphideStereochemistryOrganic ChemistryCationic polymerizationFrustrated Lewis pairInorganic ChemistryBenzaldehydechemistry.chemical_compoundchemistryPolymer chemistryPhosphoniumPhysical and Theoretical ChemistryPhosphineOrganometallics
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The Taming of Redox‐Labile Phosphidotitanocene Cations

2019

International audience; Tame d0 phosphidotitanocene cations stabilized with a pendant tertiary phosphane arm are reported. These compounds were obtained by one-electron oxidation of d1 precursors with [Cp2Fe][BPh4]. The electronic structure of these compounds was studied experimentally (EPR, UV/Vis, and NMR spectroscopy, X-ray diffraction analysis) and through DFT calculations. The theoretical analysis of the bonding situation by using the electron localization function (ELF) shows the presence of π-interactions between the phosphido ligand and Ti in the d0 complexes, whereas dπ–pπ repulsion prevents such interactions in the d1 complexes. In addition, CH–π interactions were observed in seve…

010402 general chemistry01 natural sciencesRedoxTransition metal phosphidesCatalysisFrustrated Lewis pairlaw.inventionchemistry.chemical_compoundFrustrated Lewis Pair (FLP)[CHIM.ANAL]Chemical Sciences/Analytical chemistrylaw[CHIM.COOR]Chemical Sciences/Coordination chemistryPhosphorus LigandsElectron paramagnetic resonanceDiphenylacetyleneComputingMilieux_MISCELLANEOUSTitanium[CHIM.ORGA]Chemical Sciences/Organic chemistry010405 organic chemistryLigandOrganic Chemistry[CHIM.MATE]Chemical Sciences/Material chemistryGeneral ChemistryNuclear magnetic resonance spectroscopyElectron localization function0104 chemical sciencesHomolysis[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryDensity Functional Theory (DFT)Crystallographychemistry[CHIM.CHEM]Chemical Sciences/CheminformaticsChemistry – A European Journal
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Cover Feature: A Route toward (Aminomethyl)cyclopentadienide Ligands and Their Group 4 Metal Complexes (Eur. J. Inorg. Chem. 34/2018)

2018

Inorganic ChemistryMetalFeature (computer vision)ChemistryStereochemistryGroup (periodic table)visual_artvisual_art.visual_art_mediumCover (algebra)European Journal of Inorganic Chemistry
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Reappraising Schmidpeter's bis(iminophosphoranyl)phosphides: coordination to transition metals and bonding analysis

2020

The synthesis and characterization of a range of bis(iminophosphoranyl)phosphide (BIPP) group 4 and coinage metals complexes is reported. BIPP ligands bind group 4 metals in a pseudo fac-fashion, and the central phosphorus atom enables the formation of d0–d10 heterobimetallic complexes. Various DFT computational tools (including AIM, ELF and NCI) show that the phosphorus–metal interaction is either electrostatic (Ti) or dative (Au, Cu). A bridged homobimetallic Cu–Cu complex was also prepared and its spectroscopic properties were investigated. The theoretical analysis of the P–P bond in BIPP complexes reveals that (i) BIPP are closely related to ambiphilic triphosphenium (TP) cations; (ii) …

010405 organic chemistryChemistryPhosphideCoinage metalsGeneral Chemistry010402 general chemistry01 natural sciences0104 chemical sciencesCrystallographychemistry.chemical_compoundChemistryTransition metalCovalent bondPhosphorus atom[CHIM]Chemical Sciences
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N-heterocylic and mesoionic carbene complexes of the group 4 metals

2020

International audience; N-heterocyclic carbene (NHC) complexes of group 4 metals have been far less studied than their late metal counterparts. However, the field has been explored for over 25 years, and there is now a much clearer understanding of the metal-NHC interaction. Some exceptionally robust and active catalysts have been reported for a number of group 4 metal-catalyzed reactions, and recent developments suggest that NHCs are well-suited to enable the isolation of otherwise difficult to tame species, such as low-valent complexes.

Titanium[CHIM] Chemical Sciences[CHIM]Chemical SciencesZirconiumN-Heterocyclic carbenesHafniumCatalysisCoordination chemistry
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CCDC 1421130: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, and Gerhard Erker|2015|J.Am.Chem.Soc.|137|10796|doi:10.1021/jacs.5b06551

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(eta5-cyclopentadienyl)-(di-t-butylphospheanyl)-methyl-zirconiumExperimental 3D Coordinates
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CCDC 1424182: Experimental Crystal Structure Determination

2016

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, Gerhard Erker|2016|Chem.-Eur.J.|22|4285|doi:10.1002/chem.201504792

Space GroupCrystallographyCrystal System((Dicyclohexylphosphino)methanolato)-bis(eta5-cyclopentadienyl)-methyl-zirconiumCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1871410: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(eta5-cyclopentadienyl)-dicyclohexylphosphanyl-(2-[2-(diphenylphosphanyl)ethyl]cyclopentadienyl)-titanium(iv) tetraphenylborateExperimental 3D Coordinates
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CCDC 987356: Experimental Crystal Structure Determination

2014

Related Article: Adrien T. Normand, Alexandre Massard, Philippe Richard, Coline Canovas, Cédric Balan, Michel Picquet, Audrey Auffrant, Pierre Le Gendre|2014|Dalton Trans.|43|15098|doi:10.1039/C4DT00746H

Space GroupCrystallographyCrystal System(28-dimethyl-4466-tetraphenyl-37-diaza-46-diphosphanona-36-dien-5-yl)-(tetrahydrofuran)-lithiumCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1978292: Experimental Crystal Structure Determination

2020

Related Article: Adrien T. Normand, Raluca Malacea-Kabbara, Rosita Lapenta, Aymeric Dajnak, Philippe Richard, Hélène Cattey, Anaëlle Bolley, Alfonso Grassi, Stefano Milione, Audrey Auffrant, Samuel Dagorne, Pierre Le Gendre|2020|Dalton Trans.|49|6989|doi:10.1039/D0DT00972E

Space GroupCrystallography22'-[12-phenylenebis(PP-diphenylphosphorimidoyl)]bis(46-di-t-butylphenol) 22'-[(4-bromo-12-phenylene)bis(PP-diphenylphosphorimidoyl)]bis(46-di-t-butylphenol) pentane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1871415: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(eta5-cyclopentadienyl)-(diphenylphosphanyl)-(diphenylphosphine)-titanium(iv) tetrakis(pentafluorophenyl)borateExperimental 3D Coordinates
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CCDC 1871416: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(eta5-cyclopentadienyl)-diphenylphosphanyl-(2-[2-(diphenylphosphanyl)ethyl]cyclopentadienyl)-titanium(iv) tetraphenylborate tetrahydrofuran solvateExperimental 3D Coordinates
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CCDC 1978293: Experimental Crystal Structure Determination

2020

Related Article: Adrien T. Normand, Raluca Malacea-Kabbara, Rosita Lapenta, Aymeric Dajnak, Philippe Richard, Hélène Cattey, Anaëlle Bolley, Alfonso Grassi, Stefano Milione, Audrey Auffrant, Samuel Dagorne, Pierre Le Gendre|2020|Dalton Trans.|49|6989|doi:10.1039/D0DT00972E

Space GroupCrystallographyCrystal System22'-(1166-tetraphenyl-25-diazonia-16-diphosphahexa-15-diene-16-diyl)bis(46-di-t-butylphenolate) dichloromethane solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1871408: Experimental Crystal Structure Determination

2019

Related Article: Adrien T. Normand, Quentin Bonnin, Stéphane Brandès, Philippe Richard, Paul Fleurat-Lessard, Charles H. Devillers, Cédric Balan, Pierre Le Gendre, Gerald Kehr, Gerhard Erker|2019|Chem.-Eur.J.|25|2803|doi:10.1002/chem.201805430

Space GroupCrystallographyCrystal System(eta5-cyclopentadienyl)-diphenylphosphanyl-(2-[2-(diphenylphosphanyl)ethyl]cyclopentadienyl)-titanium(iii)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1053357: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

Space GroupCrystallographyCrystal SystemCrystal Structure(1-((2-(bis(2-methylphenyl)phosphino)-1-methyl)ethyl)cyclopentadienyl)-(cyclopentadienyl)-(26-dimethylphenolato)-titanium tetraphenylborateCell ParametersExperimental 3D Coordinates
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CCDC 1978288: Experimental Crystal Structure Determination

2020

Related Article: Adrien T. Normand, Raluca Malacea-Kabbara, Rosita Lapenta, Aymeric Dajnak, Philippe Richard, Hélène Cattey, Anaëlle Bolley, Alfonso Grassi, Stefano Milione, Audrey Auffrant, Samuel Dagorne, Pierre Le Gendre|2020|Dalton Trans.|49|6989|doi:10.1039/D0DT00972E

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters{22'-[12-phenylenebis(PP-diphenylphosphorimidoyl)]bis(46-di-t-butylphenolato)}-bis(propan-2-olato)-zirconium(iv) dichloromethane unknown solvateExperimental 3D Coordinates
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CCDC 1978291: Experimental Crystal Structure Determination

2020

Related Article: Adrien T. Normand, Raluca Malacea-Kabbara, Rosita Lapenta, Aymeric Dajnak, Philippe Richard, Hélène Cattey, Anaëlle Bolley, Alfonso Grassi, Stefano Milione, Audrey Auffrant, Samuel Dagorne, Pierre Le Gendre|2020|Dalton Trans.|49|6989|doi:10.1039/D0DT00972E

Space GroupCrystallographyCrystal System22'-(1177-tetraphenyl-26-diazonia-17-diphosphahepta-16-diene-17-diyl)bis(46-di-t-butylphenolate)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1978295: Experimental Crystal Structure Determination

2020

Related Article: Adrien T. Normand, Raluca Malacea-Kabbara, Rosita Lapenta, Aymeric Dajnak, Philippe Richard, Hélène Cattey, Anaëlle Bolley, Alfonso Grassi, Stefano Milione, Audrey Auffrant, Samuel Dagorne, Pierre Le Gendre|2020|Dalton Trans.|49|6989|doi:10.1039/D0DT00972E

bis(N-methylmethanaminato)-{22'-[propane-13-diylbis(PP-diphenylphosphorimidoyl)]bis(46-di-t-butylphenolato)}-titanium(iv)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1424183: Experimental Crystal Structure Determination

2016

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, Gerhard Erker|2016|Chem.-Eur.J.|22|4285|doi:10.1002/chem.201504792

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu2-(Dicyclohexylphosphino)methanolato)-tetrakis(eta5-cyclopentadienyl)-di-zirconium tetrakis(pentafluorophenyl)borate dichloromethane solvateExperimental 3D Coordinates
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CCDC 1985146: Experimental Crystal Structure Determination

2020

Related Article: Adrien T. Normand, E. Daiann Sosa Carrizo, Corentin Magnoux, Esteban Lobato, Hélène Cattey, Philippe Richard, Stéphane Brandès, Charles H. Devillers, Anthony Romieu, Pierre Le Gendre, Paul Fleurat-Lessard|2021|Chemical Science|12|253|doi:10.1039/D0SC04736H

dichloro-[13-bis(phenylimino)-1133-tetra(propan-2-yl)-13-triphosphan-2-yl]-titanium(iii)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1985142: Experimental Crystal Structure Determination

2020

Related Article: Adrien T. Normand, E. Daiann Sosa Carrizo, Corentin Magnoux, Esteban Lobato, Hélène Cattey, Philippe Richard, Stéphane Brandès, Charles H. Devillers, Anthony Romieu, Pierre Le Gendre, Paul Fleurat-Lessard|2021|Chemical Science|12|253|doi:10.1039/D0SC04736H

bis(mu-13-bis(phenylimino)-1133-tetra(propan-2-yl)-13-triphosphan-2-yl)-bis(mu-bromo)-bis(t-butylimido)-dichloro-di-copper(i)-di-titanium(iv) dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1424177: Experimental Crystal Structure Determination

2016

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, Gerhard Erker|2016|Chem.-Eur.J.|22|4285|doi:10.1002/chem.201504792

Space GroupCrystallographybis(eta5-Cyclopentadienyl)-((dimesitylphosphino)(phenyl)methanolato)-methyl-zirconiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1985138: Experimental Crystal Structure Determination

2020

Related Article: Adrien T. Normand, E. Daiann Sosa Carrizo, Corentin Magnoux, Esteban Lobato, Hélène Cattey, Philippe Richard, Stéphane Brandès, Charles H. Devillers, Anthony Romieu, Pierre Le Gendre, Paul Fleurat-Lessard|2021|Chemical Science|12|253|doi:10.1039/D0SC04736H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(t-butylimino)-(chloro)-[N1N31133-hexaphenyl-13-triphosphane-13-diaminato]-(pyridine)-titanium(iv) unknown solvateExperimental 3D Coordinates
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CCDC 1978290: Experimental Crystal Structure Determination

2020

Related Article: Adrien T. Normand, Raluca Malacea-Kabbara, Rosita Lapenta, Aymeric Dajnak, Philippe Richard, Hélène Cattey, Anaëlle Bolley, Alfonso Grassi, Stefano Milione, Audrey Auffrant, Samuel Dagorne, Pierre Le Gendre|2020|Dalton Trans.|49|6989|doi:10.1039/D0DT00972E

Space GroupCrystallography{22'-[ethane-12-diylbis(PP-diphenylphosphorimidoyl)]bis(46-di-t-butylphenolato)}-bis(propan-2-olato)-zirconium(iv) dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1978289: Experimental Crystal Structure Determination

2020

Related Article: Adrien T. Normand, Raluca Malacea-Kabbara, Rosita Lapenta, Aymeric Dajnak, Philippe Richard, Hélène Cattey, Anaëlle Bolley, Alfonso Grassi, Stefano Milione, Audrey Auffrant, Samuel Dagorne, Pierre Le Gendre|2020|Dalton Trans.|49|6989|doi:10.1039/D0DT00972E

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-22'-[propane-13-diylbis(PP-diphenylphosphorimidoyl)]bis(46-di-t-butylphenolato))-tetrakis(benzyl)-di-zirconium(iv) unknown solvateExperimental 3D Coordinates
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CCDC 1052598: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

Space GroupCrystallography(eta5-cyclopentadienyl)-(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(4-methoxyphenolato)-titanium tetraphenylborateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1985136: Experimental Crystal Structure Determination

2020

Related Article: Adrien T. Normand, E. Daiann Sosa Carrizo, Corentin Magnoux, Esteban Lobato, Hélène Cattey, Philippe Richard, Stéphane Brandès, Charles H. Devillers, Anthony Romieu, Pierre Le Gendre, Paul Fleurat-Lessard|2021|Chemical Science|12|253|doi:10.1039/D0SC04736H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters[N1N3-diphenyl-1133-tetra(propan-2-yl)-3-triphosph-2-en-1-ium-13-bis(aminide)]-(t-butylimido)-(chloro)-titanium(iv)Experimental 3D Coordinates
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CCDC 1421134: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, and Gerhard Erker|2015|J.Am.Chem.Soc.|137|10796|doi:10.1021/jacs.5b06551

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(eta5-cyclopentadienyl)-(tert-butyl(35-dimethylphenyl)amido)-zirconium tetrakis(pentafluorophenyl)borate unknown solvateExperimental 3D Coordinates
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CCDC 1052596: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

(eta5-cyclopentadienyl)-phenolato-(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-titanium tetraphenylborateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 987359: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal System(t-butylimino)-chloro-(2288-tetramethyl-4466-tetraphenyl-37-diaza-46-diphosphanona-36-dien-5-yl)-titanium(iv) unknown solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1871418: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(3-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-diphenylphosphanyl-(eta5-cyclopentadienyl)-titanium(iii)Experimental 3D Coordinates
researchProduct

CCDC 1871412: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(eta5-cyclopentadienyl)-(2-(dicyclohexylphosphanyl)-12-diphenylethenyl)-titanium(iii)Experimental 3D Coordinates
researchProduct

CCDC 1421135: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-t-butyl(35-dimethylphenyl)carbamato)-tetrakis(eta5-cyclopentadienyl)-di-zirconium bis(methyl(tris(pentafluorophenyl))borate) unknown solvateExperimental 3D Coordinates
researchProduct

CCDC 1052597: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(eta5-cyclopentadienyl)-(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(26-dimethylphenolato)-titanium tetraphenylborate dichloromethane solvateExperimental 3D Coordinates
researchProduct

CCDC 1871414: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographybis(eta5-cyclopentadienyl)-bis(tetrahydrofuran)-titanium(iii) tetraphenylborateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1052593: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(eta5-cyclopentadienyl)-phenolato-chloro-titaniumExperimental 3D Coordinates
researchProduct

CCDC 1421138: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(eta5-cyclopentadienyl)-(3-(dicyclohexyl[12-diphenylethenyl]phosphonio)-13-diphenylprop-1-en-1-olato)-zirconium tetrakis(35-bis(trifluoromethyl)phenyl)borate unknown solvateExperimental 3D Coordinates
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CCDC 1985140: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(26-dimethylphenolato)-(1133-tetraphenyl-13-bis(phenylimino)-13-triphosphan-2-yl)-titanium(iv) tetraphenylborate dichloromethane solvateExperimental 3D Coordinates
researchProduct

CCDC 1978287: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographydibenzyl-{22'-[ethane-12-diylbis(PP-diphenylphosphorimidoyl)]bis(46-di-t-butylphenolato)}-zirconium(iv) unknown solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1053358: Experimental Crystal Structure Determination

2015

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(cyclopentadienyl)-([dicyclohexyl(2-cyclopentadienylpropan-2-yl)phosphaniumyl](phenyl)methoxy)-(26-dimethylphenolato)-titanium tetraphenylborate tetrahydrofuran solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 987357: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal SystemCrystal Structure(tetrahydrofuran)-(2288-tetramethyl-4466-tetraphenyl-37-diaza-46-diphosphanona-36-dien-5-yl)-lithiumCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1985143: Experimental Crystal Structure Determination

2020

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(1133-tetraphenyl-13-bis(phenylimino)-13-triphosphan-2-yl)-(tetrahydrofuran)-dichloro-titanium(iv)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1871411: Experimental Crystal Structure Determination

2019

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bis(eta5-cyclopentadienyl)-(2-(dicyclohexylphosphanyl)-12-diphenylethenyl)-titanium(iv) tetraphenylborateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1421133: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal Systembis(eta5-cyclopentadienyl)-(diphenylamido)-zirconium methyl(tris(pentafluorophenyl))borateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1424181: Experimental Crystal Structure Determination

2016

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Space GroupCrystallography(Dicyclohexylphosphinecarboxylato)-bis(eta5-cyclopentadienyl)-methyl-zirconiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1052592: Experimental Crystal Structure Determination

2015

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(eta5-cyclopentadienyl)-(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-dimethyl-titaniumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 987358: Experimental Crystal Structure Determination

2014

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Space GroupCrystallography(bis(NPP-triphenylphosphorimidoyl)methyl)-chloro-(t-butylimino)-titanium(iv)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1871409: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal Structure(eta5-cyclopentadienyl)-dicyclohexylphosphanyl-(2-[2-(diphenylphosphanyl)ethyl]cyclopentadienyl)-titanium(iii)Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1421131: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographybis(eta5-cyclopentadienyl)-diphenylamido-methyl-zirconiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1052595: Experimental Crystal Structure Determination

2015

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Space GroupCrystallography(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(4-methoxyphenolato)-(eta5-cyclopentadienyl)-chloro-titaniumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1052594: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(eta5-cyclopentadienyl)-chloro-(26-dimethylphenolato)-titaniumExperimental 3D Coordinates
researchProduct

CCDC 1421128: Experimental Crystal Structure Determination

2015

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bis(eta5-cyclopentadienyl)-dicyclohexylphosphanyl-methyl-zirconiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1421129: Experimental Crystal Structure Determination

2015

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bis(eta5-cyclopentadienyl)-dimesitylphosphanyl-methyl-zirconiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1871417: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(eta5-cyclopentadienyl)-diphenylphosphanyl-(2-[2-(dicyclohexylphosphanyl)ethyl]cyclopentadienyl)-titanium(iii)Experimental 3D Coordinates
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CCDC 1978294: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbenzyl-{17-bis[35-di-t-butyl-2-(oxido)phenyl]-1177-tetraphenyl-26-diaza-17-diphosphahepta-16-dien-3-yl}-zirconium(iv) n-hexane solvateExperimental 3D Coordinates
researchProduct

CCDC 1421132: Experimental Crystal Structure Determination

2015

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CCDC 1985135: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(13-bis(phenylimino)-1133-tetra(propan-2-yl)-13-triphosphan-2-ide)-trichloro-zirconium(iv)Experimental 3D Coordinates
researchProduct

CCDC 1985137: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(t-butylimino)-(chloro)-[N1N31133-hexaphenyl-13-triphosphane-13-diaminato]-(pyridine)-titanium(iv) unknown solvateExperimental 3D Coordinates
researchProduct

CCDC 1985139: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal Systembis(mu-13-bis(phenylimino)-1133-tetra(propan-2-yl)-13-triphosphan-2-yl)-di-copper(i) unknown solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1424178: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters((Di-t-butylphosphino)(phenyl)methanolato)-bis(eta5-cyclopentadienyl)-methyl-zirconiumExperimental 3D Coordinates
researchProduct

CCDC 1440373: Experimental Crystal Structure Determination

2016

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bis(cyclopentadienyl)-(1-(2-(dicyclohexylphosphanyl)phenyl)-2-phenyldiazanediido)-zirconium(iv)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1985134: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(N1N3-diphenyl-1133-tetra(propan-2-yl)-3-triphosph-2-en-1-ium-13-bis(aminide))-tetrahydrofuran-lithiumExperimental 3D Coordinates
researchProduct

CCDC 1424179: Experimental Crystal Structure Determination

2016

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Space GroupCrystallography((Dicyclohexylphosphino)(diphenyl)methanolato)-bis(eta5-cyclopentadienyl)-methyl-zirconium n-pentane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1440372: Experimental Crystal Structure Determination

2016

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bis(cyclopentadienyl)-(1-(2-(dicyclohexylphosphanyl)phenyl)-2-phenylhydrazin-1-ido)-zirconium(iv) tetrakis(pentafluorophenyl)borateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1985141: Experimental Crystal Structure Determination

2020

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trichloro-(1133-tetraphenyl-13-bis(phenylimino)-13-triphosphan-2-yl)-zirconium(iv) dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1421136: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(eta5-cyclopentadienyl)-(NN-diphenylbenzamide)-(phenylmethanolato)-zirconium tetrakis(35-bis(trifluoromethyl)phenyl)borateExperimental 3D Coordinates
researchProduct

CCDC 1985144: Experimental Crystal Structure Determination

2020

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(mu-13-bis(phenylimino)-1133-tetra(propan-2-yl)-13-triphosphan-2-yl)-(t-butylimino)-(dichloro)-titanium(iv)-gold(i) dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1871413: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-{[ferrocenyl(oxido)methyl](dicyclohexyl)phosphaniumyl}-12-diphenylethenyl)-bis(eta5-pentamethylcyclopentadienyl)-titanium(iv) tetraphenylborate dichloromethane solvateExperimental 3D Coordinates
researchProduct

CCDC 1424180: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal Structure((Di-t-butylphosphino)(diphenyl)methanolato)-bis(eta5-cyclopentadienyl)-methyl-zirconiumCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1424184: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal System(mu2-Chloro)-(mu2-(dicyclohexylphosphino)ferrocenylmethanolato-OP)-(eta3-allyl)-bis(eta5-cyclopentadienyl)-palladium-zirconium tetrakis(pentafluorophenyl)borateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1985145: Experimental Crystal Structure Determination

2020

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Space GroupCrystallographyCrystal System(t-butylimino)-(chloro)-[1133-tetraphenyl-13-bis(phenylimino)-13-triphosphan-2-yl]-titanium(iv) toluene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1421137: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(ferrocenyl(dicyclohexyl[12-diphenylethenyl]phosphonio)oxidomethyl)-zirconium tetrakis(pentafluorophenyl)borate unknown solvateExperimental 3D Coordinates
researchProduct