0000000001006020
AUTHOR
Savyasachi J. Aramballi
Sulfate-Templated 2D Anion-Layered Supramolecular Self-Assemblies
Summary Using solution and solid-state analyses, we demonstrate that the tripodal N-methylated(1,3,5-benzene-tricarboxamide)-tris(phenylurea) BTA ligands, possessing urea functionalities in the meta position, are able to form extended self-assembly 2D networks via hydrogen bonding templated by sulfate (SO42–). The divergence of the urea binding sites confers a propeller-like conformation to the ligands and is key to formation of the self-assemblies. Studies in solution and in the solid state as well as scanning electron microscopy (SEM) on the self-assembly properties of the ligands showed that the convergence also leads to the formation of hierarchical structures, including porous films an…
CCDC 1874341: Experimental Crystal Structure Determination
Related Article: Anna B. Aletti, Salvador Blasco, Savyasachi J. Aramballi, Paul E. Kruger, Thorfinnur Gunnlaugsson|2019|Chem Cell mPress|5|2617|doi:10.1016/j.chempr.2019.06.023
CCDC 1874342: Experimental Crystal Structure Determination
Related Article: Anna B. Aletti, Salvador Blasco, Savyasachi J. Aramballi, Paul E. Kruger, Thorfinnur Gunnlaugsson|2019|Chem Cell mPress|5|2617|doi:10.1016/j.chempr.2019.06.023
CCDC 1874344: Experimental Crystal Structure Determination
Related Article: Anna B. Aletti, Salvador Blasco, Savyasachi J. Aramballi, Paul E. Kruger, Thorfinnur Gunnlaugsson|2019|Chem Cell mPress|5|2617|doi:10.1016/j.chempr.2019.06.023