Author: A. Peuronen

0000000001017853

AUTHOR

A. Peuronen

One‐pot synthesis of [2+2]‐helicate‐like macrocycle and 2+4‐μ4‐oxo tetranuclear open frame complexes : Chiroptical properties and asymmetric oxidative coupling of 2‐naphthols

Synthesis of binuclear Cu(II) terminally closed [2+2]‐ double‐stranded helicate‐like macrocycles 1, 1′,1″, 2, 2′, 2″ and 2+4‐μ4‐oxo tetranuclear open frame complexes 3, 3′, 3″, 4, 4′, 4″ are established. Adapting one‐pot self‐assembly technique from simple three components systems: 1,1′‐binaphthyl‐2,2′‐diamine, 4‐methyl‐2,6‐diformyl phenol and cupric salts, the helicate‐like [2+2]‐ macrocyclic complexes 1–1″, 2–2″ and 2+4‐μ4‐oxo tetranuclear complexes 3–3″, 4–4″ were obtained by appropriately altering the reaction condition such as temperature and subcomponent ratio. Density Functional Theory (DFT) calculations were carried out for understanding the structural geometries, intermediates invo…

0000000001017853

AUTHOR

A. Peuronen

One‐pot synthesis of [2+2]‐helicate‐like macrocycle and 2+4‐μ4‐oxo tetranuclear open frame complexes : Chiroptical properties and asymmetric oxidative coupling of 2‐naphthols

CCDC 703947: Experimental Crystal Structure Determination

CCDC 1052253: Experimental Crystal Structure Determination

CCDC 977973: Experimental Crystal Structure Determination

CCDC 889688: Experimental Crystal Structure Determination

CCDC 879930: Experimental Crystal Structure Determination

CCDC 977976: Experimental Crystal Structure Determination

CCDC 879931: Experimental Crystal Structure Determination

CCDC 977975: Experimental Crystal Structure Determination

CCDC 1052252: Experimental Crystal Structure Determination

CCDC 692357: Experimental Crystal Structure Determination

CCDC 879941: Experimental Crystal Structure Determination

CCDC 703948: Experimental Crystal Structure Determination

CCDC 692351: Experimental Crystal Structure Determination

CCDC 879940: Experimental Crystal Structure Determination

CCDC 692354: Experimental Crystal Structure Determination

CCDC 879939: Experimental Crystal Structure Determination

CCDC 879937: Experimental Crystal Structure Determination

CCDC 703944: Experimental Crystal Structure Determination

CCDC 692352: Experimental Crystal Structure Determination

CCDC 957912: Experimental Crystal Structure Determination

CCDC 977974: Experimental Crystal Structure Determination

CCDC 957913: Experimental Crystal Structure Determination

CCDC 879929: Experimental Crystal Structure Determination

CCDC 703945: Experimental Crystal Structure Determination

CCDC 879935: Experimental Crystal Structure Determination

CCDC 879936: Experimental Crystal Structure Determination

CCDC 914185: Experimental Crystal Structure Determination

CCDC 879942: Experimental Crystal Structure Determination

CCDC 692355: Experimental Crystal Structure Determination

CCDC 957911: Experimental Crystal Structure Determination

CCDC 692353: Experimental Crystal Structure Determination

CCDC 1052255: Experimental Crystal Structure Determination

CCDC 703946: Experimental Crystal Structure Determination

CCDC 879933: Experimental Crystal Structure Determination

CCDC 879938: Experimental Crystal Structure Determination

CCDC 879934: Experimental Crystal Structure Determination

CCDC 1052251: Experimental Crystal Structure Determination

CCDC 879932: Experimental Crystal Structure Determination

CCDC 1052254: Experimental Crystal Structure Determination

CCDC 692356: Experimental Crystal Structure Determination