0000000001020323

AUTHOR

J. Roth

A new BEDT-TTF salt and polypyrrole films containing the chiral polyoxometalate [H4Co2Mo10O38]6−

Abstract The chiral polyoxometalate [H4Co2Mo10O38]6− has been used in the preparation of hybrid materials in the form of crystals or polymeric films. A new radical salt of the donor bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF or ET) containing the two enantiomers of this polyoxometalate has been obtained by electrocrystallization. This radical salt shows semiconducting behavior with room temperature conductivity of 9 S.cm−1 and activation energy of 40 meV. Polypyrrole films doped with a racemic mixture of polyoxometalates and also the enantiomerically pure (+)589-[H4Co2Mo10O38]6− have been prepared electrochemically. Circular dichroism experiments suggest that the chiral polyoxometalate…

research product

Abstract of the 68th Meeting (Spring Meeting) 6–9 March 1990, Heidelberg

research product

An improved method for measuring muon energy using the truncated mean of dE/dx

Nuclear instruments & methods in physics research / A 703, 190 - 198 (2013). doi:10.1016/j.nima.2012.11.081

research product

IceTop : the surface component of IceCube

IceTop, the surface component of the IceCube Neutrino Observatory at the South Pole, is an air shower array with an area of 1 km2. The detector allows a detailed exploration of the mass composition of primary cosmic rays in the energy range from about 100 TeV to 1 EeV by exploiting the correlation between the shower energy measured in IceTop and the energy deposited by muons in the deep ice. In this paper we report on the technical design, construction and installation, the trigger and data acquisition systems as well as the software framework for calibration, reconstruction and simulation. Finally the first experience from commissioning and operating the detector and the performance as an …

research product